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Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-dysprosium(III)silver(I)] perchlorate]

In the title three-dimensional heterometallic complex, {[AgDy(C(6)H(4)NO(2))(2)(C(2)H(3)O(2))(H(2)O)]ClO(4)}(n), the Dy(III) ion is eight-coordinated by four O atoms from four different isonicotinate ligands, three O atoms from two different acetate ligands and one O atom of water mol­ecule. The two...

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Detalles Bibliográficos
Autor principal: Zhu, Li-Cai
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972040/
https://www.ncbi.nlm.nih.gov/pubmed/21578624
http://dx.doi.org/10.1107/S1600536809046637
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author Zhu, Li-Cai
author_facet Zhu, Li-Cai
author_sort Zhu, Li-Cai
collection PubMed
description In the title three-dimensional heterometallic complex, {[AgDy(C(6)H(4)NO(2))(2)(C(2)H(3)O(2))(H(2)O)]ClO(4)}(n), the Dy(III) ion is eight-coordinated by four O atoms from four different isonicotinate ligands, three O atoms from two different acetate ligands and one O atom of water mol­ecule. The two-coordinate Ag(I) ion is bonded to two N atoms from two different isonicotinate anions. These metal coordination units are connected by bridging isonicotinate and acetate ligands, generating a three-dimensional network. The coordinated water mol­ecules link the carboxyl­ate group and the acetate ligand by O—H⋯O hydrogen bonding. The perchlorate anion is disordered over two sites with site occupancy factors 0.508 (12) and 0.492 (12) and the methyl group of the acetate ligand is disordered over two positions of equal occupancy.
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spelling pubmed-29720402010-12-30 Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-dysprosium(III)silver(I)] perchlorate] Zhu, Li-Cai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title three-dimensional heterometallic complex, {[AgDy(C(6)H(4)NO(2))(2)(C(2)H(3)O(2))(H(2)O)]ClO(4)}(n), the Dy(III) ion is eight-coordinated by four O atoms from four different isonicotinate ligands, three O atoms from two different acetate ligands and one O atom of water mol­ecule. The two-coordinate Ag(I) ion is bonded to two N atoms from two different isonicotinate anions. These metal coordination units are connected by bridging isonicotinate and acetate ligands, generating a three-dimensional network. The coordinated water mol­ecules link the carboxyl­ate group and the acetate ligand by O—H⋯O hydrogen bonding. The perchlorate anion is disordered over two sites with site occupancy factors 0.508 (12) and 0.492 (12) and the methyl group of the acetate ligand is disordered over two positions of equal occupancy. International Union of Crystallography 2009-11-18 /pmc/articles/PMC2972040/ /pubmed/21578624 http://dx.doi.org/10.1107/S1600536809046637 Text en © Li-Cai Zhu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Li-Cai
Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-dysprosium(III)silver(I)] perchlorate]
title Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-dysprosium(III)silver(I)] perchlorate]
title_full Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-dysprosium(III)silver(I)] perchlorate]
title_fullStr Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-dysprosium(III)silver(I)] perchlorate]
title_full_unstemmed Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-dysprosium(III)silver(I)] perchlorate]
title_short Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-dysprosium(III)silver(I)] perchlorate]
title_sort poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-dysprosium(iii)silver(i)] perchlorate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972040/
https://www.ncbi.nlm.nih.gov/pubmed/21578624
http://dx.doi.org/10.1107/S1600536809046637
work_keys_str_mv AT zhulicai polym2acetatoaquadim3isonicotinatodysprosiumiiisilveriperchlorate