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Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-dysprosium(III)silver(I)] perchlorate]
In the title three-dimensional heterometallic complex, {[AgDy(C(6)H(4)NO(2))(2)(C(2)H(3)O(2))(H(2)O)]ClO(4)}(n), the Dy(III) ion is eight-coordinated by four O atoms from four different isonicotinate ligands, three O atoms from two different acetate ligands and one O atom of water molecule. The two...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972040/ https://www.ncbi.nlm.nih.gov/pubmed/21578624 http://dx.doi.org/10.1107/S1600536809046637 |
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author | Zhu, Li-Cai |
author_facet | Zhu, Li-Cai |
author_sort | Zhu, Li-Cai |
collection | PubMed |
description | In the title three-dimensional heterometallic complex, {[AgDy(C(6)H(4)NO(2))(2)(C(2)H(3)O(2))(H(2)O)]ClO(4)}(n), the Dy(III) ion is eight-coordinated by four O atoms from four different isonicotinate ligands, three O atoms from two different acetate ligands and one O atom of water molecule. The two-coordinate Ag(I) ion is bonded to two N atoms from two different isonicotinate anions. These metal coordination units are connected by bridging isonicotinate and acetate ligands, generating a three-dimensional network. The coordinated water molecules link the carboxylate group and the acetate ligand by O—H⋯O hydrogen bonding. The perchlorate anion is disordered over two sites with site occupancy factors 0.508 (12) and 0.492 (12) and the methyl group of the acetate ligand is disordered over two positions of equal occupancy. |
format | Text |
id | pubmed-2972040 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29720402010-12-30 Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-dysprosium(III)silver(I)] perchlorate] Zhu, Li-Cai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title three-dimensional heterometallic complex, {[AgDy(C(6)H(4)NO(2))(2)(C(2)H(3)O(2))(H(2)O)]ClO(4)}(n), the Dy(III) ion is eight-coordinated by four O atoms from four different isonicotinate ligands, three O atoms from two different acetate ligands and one O atom of water molecule. The two-coordinate Ag(I) ion is bonded to two N atoms from two different isonicotinate anions. These metal coordination units are connected by bridging isonicotinate and acetate ligands, generating a three-dimensional network. The coordinated water molecules link the carboxylate group and the acetate ligand by O—H⋯O hydrogen bonding. The perchlorate anion is disordered over two sites with site occupancy factors 0.508 (12) and 0.492 (12) and the methyl group of the acetate ligand is disordered over two positions of equal occupancy. International Union of Crystallography 2009-11-18 /pmc/articles/PMC2972040/ /pubmed/21578624 http://dx.doi.org/10.1107/S1600536809046637 Text en © Li-Cai Zhu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhu, Li-Cai Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-dysprosium(III)silver(I)] perchlorate] |
title | Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-dysprosium(III)silver(I)] perchlorate] |
title_full | Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-dysprosium(III)silver(I)] perchlorate] |
title_fullStr | Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-dysprosium(III)silver(I)] perchlorate] |
title_full_unstemmed | Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-dysprosium(III)silver(I)] perchlorate] |
title_short | Poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-dysprosium(III)silver(I)] perchlorate] |
title_sort | poly[[μ(2)-acetato-aquadi-μ(3)-isonicotinato-dysprosium(iii)silver(i)] perchlorate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972040/ https://www.ncbi.nlm.nih.gov/pubmed/21578624 http://dx.doi.org/10.1107/S1600536809046637 |
work_keys_str_mv | AT zhulicai polym2acetatoaquadim3isonicotinatodysprosiumiiisilveriperchlorate |