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3-Benzyl-7-chloro-9-phenyl-2-tosyl-2,3,3a,4,9,9a-hexa­hydro-1H-pyrrolo[3,4-b]quinoline

In the title compound, C(31)H(29)ClN(2)O(2)S, the pyrrolidine ring adopts an envelope conformation with the methine C atom adjacent to the NH group as the flap atom. The tetra­hydro­pyridine ring has a half-chair conformation. The two rings are trans-fused. The chloro­benzene ring and the adjacent p...

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Detalles Bibliográficos
Autores principales: Chinnakali, K., Sudha, D., Jayagobi, M., Raghunathan, R., Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972055/
https://www.ncbi.nlm.nih.gov/pubmed/21578714
http://dx.doi.org/10.1107/S1600536809045267
Descripción
Sumario:In the title compound, C(31)H(29)ClN(2)O(2)S, the pyrrolidine ring adopts an envelope conformation with the methine C atom adjacent to the NH group as the flap atom. The tetra­hydro­pyridine ring has a half-chair conformation. The two rings are trans-fused. The chloro­benzene ring and the adjacent phenyl ring form a dihedral angle of 77.9 (1)°. The benzyl phenyl and the tosyl phenyl rings are oriented at a dihedral angle of 88.0 (1)°. In the crystal, mol­ecules are linked into chains along the a axis by N—H⋯Cl and C—H⋯Cl hydrogen bonds and the adjacent chains are cross-linked via C—H⋯π inter­actions.