Bis{μ-1,3-bis­[2-(5-bromo-2-oxidobenzyl­idene­amino)ethyl]-2-(5-bromo-2-oxido­phenyl)-1,3-imidazolidine}dineo­dymium(III) N,N-dimethyl­formamide hexa­solvate

In the title centrosymmetric dinuclear complex, [Nd(2)(C(27)H(24)Br(3)N(4)O(3))(2)]·6C(3)H(7)NO, the Nd(III) ion is coordinated in a slightly distorted square-anti­prismatic geometry by four N atoms and four O atoms from two centrosymmetrically-related 1,3-bis­[2-(5-bromo-2-oxidobenzyl­amino)eth­yl]...

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Detalles Bibliográficos
Autores principales: Xie, Qing-Fan, Huang, Miao-Ling, Chen, Yan-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972062/
https://www.ncbi.nlm.nih.gov/pubmed/21578671
http://dx.doi.org/10.1107/S1600536809047564
Descripción
Sumario:In the title centrosymmetric dinuclear complex, [Nd(2)(C(27)H(24)Br(3)N(4)O(3))(2)]·6C(3)H(7)NO, the Nd(III) ion is coordinated in a slightly distorted square-anti­prismatic geometry by four N atoms and four O atoms from two centrosymmetrically-related 1,3-bis­[2-(5-bromo-2-oxidobenzyl­amino)eth­yl]-2-(5-bromo-2-oxidophen­yl)-1,3-imidazolidine ligands. The Nd⋯Nd separation is 4.5012 (12) Å.

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