Bis{μ-1,3-bis­[2-(5-bromo-2-oxidobenzyl­idene­amino)ethyl]-2-(5-bromo-2-oxido­phenyl)-1,3-imidazolidine}dineo­dymium(III) N,N-dimethyl­formamide hexa­solvate

In the title centrosymmetric dinuclear complex, [Nd(2)(C(27)H(24)Br(3)N(4)O(3))(2)]·6C(3)H(7)NO, the Nd(III) ion is coordinated in a slightly distorted square-anti­prismatic geometry by four N atoms and four O atoms from two centrosymmetrically-related 1,3-bis­[2-(5-bromo-2-oxidobenzyl­amino)eth­yl]...

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Detalles Bibliográficos
Autores principales: Xie, Qing-Fan, Huang, Miao-Ling, Chen, Yan-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972062/
https://www.ncbi.nlm.nih.gov/pubmed/21578671
http://dx.doi.org/10.1107/S1600536809047564
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author Xie, Qing-Fan
Huang, Miao-Ling
Chen, Yan-Min
author_facet Xie, Qing-Fan
Huang, Miao-Ling
Chen, Yan-Min
author_sort Xie, Qing-Fan
collection PubMed
description In the title centrosymmetric dinuclear complex, [Nd(2)(C(27)H(24)Br(3)N(4)O(3))(2)]·6C(3)H(7)NO, the Nd(III) ion is coordinated in a slightly distorted square-anti­prismatic geometry by four N atoms and four O atoms from two centrosymmetrically-related 1,3-bis­[2-(5-bromo-2-oxidobenzyl­amino)eth­yl]-2-(5-bromo-2-oxidophen­yl)-1,3-imidazolidine ligands. The Nd⋯Nd separation is 4.5012 (12) Å.
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spelling pubmed-29720622010-12-30 Bis{μ-1,3-bis­[2-(5-bromo-2-oxidobenzyl­idene­amino)ethyl]-2-(5-bromo-2-oxido­phenyl)-1,3-imidazolidine}dineo­dymium(III) N,N-dimethyl­formamide hexa­solvate Xie, Qing-Fan Huang, Miao-Ling Chen, Yan-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric dinuclear complex, [Nd(2)(C(27)H(24)Br(3)N(4)O(3))(2)]·6C(3)H(7)NO, the Nd(III) ion is coordinated in a slightly distorted square-anti­prismatic geometry by four N atoms and four O atoms from two centrosymmetrically-related 1,3-bis­[2-(5-bromo-2-oxidobenzyl­amino)eth­yl]-2-(5-bromo-2-oxidophen­yl)-1,3-imidazolidine ligands. The Nd⋯Nd separation is 4.5012 (12) Å. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2972062/ /pubmed/21578671 http://dx.doi.org/10.1107/S1600536809047564 Text en © Xie et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xie, Qing-Fan
Huang, Miao-Ling
Chen, Yan-Min
Bis{μ-1,3-bis­[2-(5-bromo-2-oxidobenzyl­idene­amino)ethyl]-2-(5-bromo-2-oxido­phenyl)-1,3-imidazolidine}dineo­dymium(III) N,N-dimethyl­formamide hexa­solvate
title Bis{μ-1,3-bis­[2-(5-bromo-2-oxidobenzyl­idene­amino)ethyl]-2-(5-bromo-2-oxido­phenyl)-1,3-imidazolidine}dineo­dymium(III) N,N-dimethyl­formamide hexa­solvate
title_full Bis{μ-1,3-bis­[2-(5-bromo-2-oxidobenzyl­idene­amino)ethyl]-2-(5-bromo-2-oxido­phenyl)-1,3-imidazolidine}dineo­dymium(III) N,N-dimethyl­formamide hexa­solvate
title_fullStr Bis{μ-1,3-bis­[2-(5-bromo-2-oxidobenzyl­idene­amino)ethyl]-2-(5-bromo-2-oxido­phenyl)-1,3-imidazolidine}dineo­dymium(III) N,N-dimethyl­formamide hexa­solvate
title_full_unstemmed Bis{μ-1,3-bis­[2-(5-bromo-2-oxidobenzyl­idene­amino)ethyl]-2-(5-bromo-2-oxido­phenyl)-1,3-imidazolidine}dineo­dymium(III) N,N-dimethyl­formamide hexa­solvate
title_short Bis{μ-1,3-bis­[2-(5-bromo-2-oxidobenzyl­idene­amino)ethyl]-2-(5-bromo-2-oxido­phenyl)-1,3-imidazolidine}dineo­dymium(III) N,N-dimethyl­formamide hexa­solvate
title_sort bis{μ-1,3-bis­[2-(5-bromo-2-oxidobenzyl­idene­amino)ethyl]-2-(5-bromo-2-oxido­phenyl)-1,3-imidazolidine}dineo­dymium(iii) n,n-dimethyl­formamide hexa­solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972062/
https://www.ncbi.nlm.nih.gov/pubmed/21578671
http://dx.doi.org/10.1107/S1600536809047564
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AT huangmiaoling bism13bis25bromo2oxidobenzylideneaminoethyl25bromo2oxidophenyl13imidazolidinedineodymiumiiinndimethylformamidehexasolvate
AT chenyanmin bism13bis25bromo2oxidobenzylideneaminoethyl25bromo2oxidophenyl13imidazolidinedineodymiumiiinndimethylformamidehexasolvate

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