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Tetra-μ-acetato-κ(8) O:O′-bis­{[2-(m-tolyl­amino)pyridine-κN]copper(II)}

In the crystal structure of the title compound, [Cu(2)(C(2)H(3)O(2))(4)(C(12)H(12)N(2))(2)], the binuclear mol­ecule lies about a center of inversion; the four acetate groups each bridge a pair of Cu(II) atoms. The coordination of the metal atom is distorted square-pyramidal, with the bonding O atom...

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Detalles Bibliográficos
Autores principales: Fairuz, Zainal Abidin, Aiyub, Zaharah, Abdullah, Zanariah, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972063/
https://www.ncbi.nlm.nih.gov/pubmed/21578695
http://dx.doi.org/10.1107/S1600536809050041
Descripción
Sumario:In the crystal structure of the title compound, [Cu(2)(C(2)H(3)O(2))(4)(C(12)H(12)N(2))(2)], the binuclear mol­ecule lies about a center of inversion; the four acetate groups each bridge a pair of Cu(II) atoms. The coordination of the metal atom is distorted square-pyramidal, with the bonding O atoms comprising a square basal plane and the coordinating N atom of the N-heterocycle occupying the apical position. The pyridine ring is twisted with respect to the benzene ring at a dihedral angle of 45.68 (16)°. Intra­molecular N—H⋯O hydrogen bonding is present between the imino and carb­oxy groups.