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Bis(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))bis(4-methylbenzoato-κO)copper(II)
In title compound, [Cu(C(8)H(7)O(2))(2)(C(6)H(6)N(4))(2)], the Cu(II) atom (site symmetry [Image: see text]) is coordinated by two N,N′-bidentate 2,2′-biimidazole ligands and two weakly bonded 4-methylbenzoate anions, resulting in a strongly elongated trans-CuO(2)N(4) octahedral geometry. In the c...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972066/ https://www.ncbi.nlm.nih.gov/pubmed/21578549 http://dx.doi.org/10.1107/S1600536809044262 |
Sumario: | In title compound, [Cu(C(8)H(7)O(2))(2)(C(6)H(6)N(4))(2)], the Cu(II) atom (site symmetry [Image: see text]) is coordinated by two N,N′-bidentate 2,2′-biimidazole ligands and two weakly bonded 4-methylbenzoate anions, resulting in a strongly elongated trans-CuO(2)N(4) octahedral geometry. In the crystal, adjacent molecules are linked via pairs of N—H⋯O hydrogen bonds into chains propagating in [010]. |
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