Bis(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))bis­(4-methyl­benzoato-κO)copper(II)

In title compound, [Cu(C(8)H(7)O(2))(2)(C(6)H(6)N(4))(2)], the Cu(II) atom (site symmetry [Image: see text]) is coordinated by two N,N′-bidentate 2,2′-biimidazole ligands and two weakly bonded 4-methyl­benzoate anions, resulting in a strongly elongated trans-CuO(2)N(4) octa­hedral geometry. In the c...

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Detalles Bibliográficos
Autor principal: Hui, Zhou
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972066/
https://www.ncbi.nlm.nih.gov/pubmed/21578549
http://dx.doi.org/10.1107/S1600536809044262
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author Hui, Zhou
author_facet Hui, Zhou
author_sort Hui, Zhou
collection PubMed
description In title compound, [Cu(C(8)H(7)O(2))(2)(C(6)H(6)N(4))(2)], the Cu(II) atom (site symmetry [Image: see text]) is coordinated by two N,N′-bidentate 2,2′-biimidazole ligands and two weakly bonded 4-methyl­benzoate anions, resulting in a strongly elongated trans-CuO(2)N(4) octa­hedral geometry. In the crystal, adjacent mol­ecules are linked via pairs of N—H⋯O hydrogen bonds into chains propagating in [010].
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spelling pubmed-29720662010-12-30 Bis(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))bis­(4-methyl­benzoato-κO)copper(II) Hui, Zhou Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In title compound, [Cu(C(8)H(7)O(2))(2)(C(6)H(6)N(4))(2)], the Cu(II) atom (site symmetry [Image: see text]) is coordinated by two N,N′-bidentate 2,2′-biimidazole ligands and two weakly bonded 4-methyl­benzoate anions, resulting in a strongly elongated trans-CuO(2)N(4) octa­hedral geometry. In the crystal, adjacent mol­ecules are linked via pairs of N—H⋯O hydrogen bonds into chains propagating in [010]. International Union of Crystallography 2009-11-04 /pmc/articles/PMC2972066/ /pubmed/21578549 http://dx.doi.org/10.1107/S1600536809044262 Text en © Zhou Hui 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hui, Zhou
Bis(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))bis­(4-methyl­benzoato-κO)copper(II)
title Bis(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))bis­(4-methyl­benzoato-κO)copper(II)
title_full Bis(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))bis­(4-methyl­benzoato-κO)copper(II)
title_fullStr Bis(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))bis­(4-methyl­benzoato-κO)copper(II)
title_full_unstemmed Bis(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))bis­(4-methyl­benzoato-κO)copper(II)
title_short Bis(2,2′-bi-1H-imidazole-κ(2) N (3),N (3′))bis­(4-methyl­benzoato-κO)copper(II)
title_sort bis(2,2′-bi-1h-imidazole-κ(2) n (3),n (3′))bis­(4-methyl­benzoato-κo)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972066/
https://www.ncbi.nlm.nih.gov/pubmed/21578549
http://dx.doi.org/10.1107/S1600536809044262
work_keys_str_mv AT huizhou bis22bi1himidazolek2n3n3bis4methylbenzoatokocopperii

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