Diaqua­bis(2,4-dichloro-6-formyl­phenolato)zinc(II)–bis­(μ-2,4-dichloro-6-formyl­phenolato)bis­[aqua­(2,4-dichloro-6-formyl­phenolato)zinc(II)] (2/1)

The crystal of the title compound, [Zn(C(7)H(3)Cl(2)O(2))(2)(H(2)O)(2)](2)·[Zn(2)(C(7)H(3)Cl(2)O(2))(4)(H(2)O)(2)], consists of monomeric and dimeric Zn(II) complexes. Both complexes afford a six-coordinated coordination environment about the Zn atoms with cis-configuration ligands. The deprotonated...

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Detalles Bibliográficos
Autores principales: Watanabe, Yoshimasa, Aritake, Yoshikazu, Akitsu, Takashiro
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972068/
https://www.ncbi.nlm.nih.gov/pubmed/21578655
http://dx.doi.org/10.1107/S160053680904896X
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author Watanabe, Yoshimasa
Aritake, Yoshikazu
Akitsu, Takashiro
author_facet Watanabe, Yoshimasa
Aritake, Yoshikazu
Akitsu, Takashiro
author_sort Watanabe, Yoshimasa
collection PubMed
description The crystal of the title compound, [Zn(C(7)H(3)Cl(2)O(2))(2)(H(2)O)(2)](2)·[Zn(2)(C(7)H(3)Cl(2)O(2))(4)(H(2)O)(2)], consists of monomeric and dimeric Zn(II) complexes. Both complexes afford a six-coordinated coordination environment about the Zn atoms with cis-configuration ligands. The deprotonated hydr­oxy groups of the 3,5-dichloro­salicylaldehyde ligands bridge two metal cations, forming a centrosymmetric dimeric complex. Inter­molecular O—H⋯O hydrogen bonding occurs between the coordinated water mol­ecules and deprotonated hydr­oxy groups in the crystal structure.
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spelling pubmed-29720682010-12-30 Diaqua­bis(2,4-dichloro-6-formyl­phenolato)zinc(II)–bis­(μ-2,4-dichloro-6-formyl­phenolato)bis­[aqua­(2,4-dichloro-6-formyl­phenolato)zinc(II)] (2/1) Watanabe, Yoshimasa Aritake, Yoshikazu Akitsu, Takashiro Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal of the title compound, [Zn(C(7)H(3)Cl(2)O(2))(2)(H(2)O)(2)](2)·[Zn(2)(C(7)H(3)Cl(2)O(2))(4)(H(2)O)(2)], consists of monomeric and dimeric Zn(II) complexes. Both complexes afford a six-coordinated coordination environment about the Zn atoms with cis-configuration ligands. The deprotonated hydr­oxy groups of the 3,5-dichloro­salicylaldehyde ligands bridge two metal cations, forming a centrosymmetric dimeric complex. Inter­molecular O—H⋯O hydrogen bonding occurs between the coordinated water mol­ecules and deprotonated hydr­oxy groups in the crystal structure. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2972068/ /pubmed/21578655 http://dx.doi.org/10.1107/S160053680904896X Text en © Watanabe et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Watanabe, Yoshimasa
Aritake, Yoshikazu
Akitsu, Takashiro
Diaqua­bis(2,4-dichloro-6-formyl­phenolato)zinc(II)–bis­(μ-2,4-dichloro-6-formyl­phenolato)bis­[aqua­(2,4-dichloro-6-formyl­phenolato)zinc(II)] (2/1)
title Diaqua­bis(2,4-dichloro-6-formyl­phenolato)zinc(II)–bis­(μ-2,4-dichloro-6-formyl­phenolato)bis­[aqua­(2,4-dichloro-6-formyl­phenolato)zinc(II)] (2/1)
title_full Diaqua­bis(2,4-dichloro-6-formyl­phenolato)zinc(II)–bis­(μ-2,4-dichloro-6-formyl­phenolato)bis­[aqua­(2,4-dichloro-6-formyl­phenolato)zinc(II)] (2/1)
title_fullStr Diaqua­bis(2,4-dichloro-6-formyl­phenolato)zinc(II)–bis­(μ-2,4-dichloro-6-formyl­phenolato)bis­[aqua­(2,4-dichloro-6-formyl­phenolato)zinc(II)] (2/1)
title_full_unstemmed Diaqua­bis(2,4-dichloro-6-formyl­phenolato)zinc(II)–bis­(μ-2,4-dichloro-6-formyl­phenolato)bis­[aqua­(2,4-dichloro-6-formyl­phenolato)zinc(II)] (2/1)
title_short Diaqua­bis(2,4-dichloro-6-formyl­phenolato)zinc(II)–bis­(μ-2,4-dichloro-6-formyl­phenolato)bis­[aqua­(2,4-dichloro-6-formyl­phenolato)zinc(II)] (2/1)
title_sort diaqua­bis(2,4-dichloro-6-formyl­phenolato)zinc(ii)–bis­(μ-2,4-dichloro-6-formyl­phenolato)bis­[aqua­(2,4-dichloro-6-formyl­phenolato)zinc(ii)] (2/1)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972068/
https://www.ncbi.nlm.nih.gov/pubmed/21578655
http://dx.doi.org/10.1107/S160053680904896X
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AT aritakeyoshikazu diaquabis24dichloro6formylphenolatozinciibism24dichloro6formylphenolatobisaqua24dichloro6formylphenolatozincii21
AT akitsutakashiro diaquabis24dichloro6formylphenolatozinciibism24dichloro6formylphenolatobisaqua24dichloro6formylphenolatozincii21

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