[(Z)-N-Isopropyl-O-methyl­thio­carbamato-κS](tri-p-tolyl­phosphine-κP)gold(I)

In the title compound, [Au(C(5)H(10)NOS)(C(21)H(21)P)], two independent mol­ecules comprise the asymmetric unit, and these are connected by an aurophilic inter­action [Au⋯Au = 3.1351 (3) Å]. Each Au(I) atom is linearly coordinated within a S,P-donor set with the distortion from ideal linear geometry...

Descripción completa

Detalles Bibliográficos
Autores principales: Tadbuppa, Primjira P., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972070/
https://www.ncbi.nlm.nih.gov/pubmed/21578594
http://dx.doi.org/10.1107/S1600536809046893
_version_ 1782190737123704832
author Tadbuppa, Primjira P.
Tiekink, Edward R. T.
author_facet Tadbuppa, Primjira P.
Tiekink, Edward R. T.
author_sort Tadbuppa, Primjira P.
collection PubMed
description In the title compound, [Au(C(5)H(10)NOS)(C(21)H(21)P)], two independent mol­ecules comprise the asymmetric unit, and these are connected by an aurophilic inter­action [Au⋯Au = 3.1351 (3) Å]. Each Au(I) atom is linearly coordinated within a S,P-donor set with the distortion from ideal linear geometry [S—Au—P = 175.31 (5) and 176.45 (5)°] ascribed to an intra­molecular Au⋯O contact in each case [2.974 (4) and 3.027 (4) Å].
format Text
id pubmed-2972070
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29720702010-12-30 [(Z)-N-Isopropyl-O-methyl­thio­carbamato-κS](tri-p-tolyl­phosphine-κP)gold(I) Tadbuppa, Primjira P. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Au(C(5)H(10)NOS)(C(21)H(21)P)], two independent mol­ecules comprise the asymmetric unit, and these are connected by an aurophilic inter­action [Au⋯Au = 3.1351 (3) Å]. Each Au(I) atom is linearly coordinated within a S,P-donor set with the distortion from ideal linear geometry [S—Au—P = 175.31 (5) and 176.45 (5)°] ascribed to an intra­molecular Au⋯O contact in each case [2.974 (4) and 3.027 (4) Å]. International Union of Crystallography 2009-11-11 /pmc/articles/PMC2972070/ /pubmed/21578594 http://dx.doi.org/10.1107/S1600536809046893 Text en © Tadbuppa and Tiekink 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tadbuppa, Primjira P.
Tiekink, Edward R. T.
[(Z)-N-Isopropyl-O-methyl­thio­carbamato-κS](tri-p-tolyl­phosphine-κP)gold(I)
title [(Z)-N-Isopropyl-O-methyl­thio­carbamato-κS](tri-p-tolyl­phosphine-κP)gold(I)
title_full [(Z)-N-Isopropyl-O-methyl­thio­carbamato-κS](tri-p-tolyl­phosphine-κP)gold(I)
title_fullStr [(Z)-N-Isopropyl-O-methyl­thio­carbamato-κS](tri-p-tolyl­phosphine-κP)gold(I)
title_full_unstemmed [(Z)-N-Isopropyl-O-methyl­thio­carbamato-κS](tri-p-tolyl­phosphine-κP)gold(I)
title_short [(Z)-N-Isopropyl-O-methyl­thio­carbamato-κS](tri-p-tolyl­phosphine-κP)gold(I)
title_sort [(z)-n-isopropyl-o-methyl­thio­carbamato-κs](tri-p-tolyl­phosphine-κp)gold(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972070/
https://www.ncbi.nlm.nih.gov/pubmed/21578594
http://dx.doi.org/10.1107/S1600536809046893
work_keys_str_mv AT tadbuppaprimjirap znisopropylomethylthiocarbamatokstriptolylphosphinekpgoldi
AT tiekinkedwardrt znisopropylomethylthiocarbamatokstriptolylphosphinekpgoldi

Ejemplares similares