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Bis{μ-4′-[4-(quinolin-8-yloxymethyl)phenyl]-2,2′:6′,2′′-terpyridine}disilver(I) bis(perchlorate) dimethylformamide disolvate
In the binuclear title complex, [Ag(2)(C(31)H(22)N(4)O)(2)](ClO(4))(2)·2C(3)H(7)NO, the Ag(I) atom is pentacoordinated by three N atoms from the tridentate chelating terpyridyl group and by one N atom and one O atom from the quinolin-8-yloxy group in a distorted square-pyramidal geometry with the...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972071/ https://www.ncbi.nlm.nih.gov/pubmed/21578682 http://dx.doi.org/10.1107/S1600536809046832 |
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| author | Chen, Chang-Juan Liu, Feng-Neng Zhang, Ai-Jiang Zhang, Liang-Wei Liu, Xiang |
| author_facet | Chen, Chang-Juan Liu, Feng-Neng Zhang, Ai-Jiang Zhang, Liang-Wei Liu, Xiang |
| author_sort | Chen, Chang-Juan |
| collection | PubMed |
| description | In the binuclear title complex, [Ag(2)(C(31)H(22)N(4)O)(2)](ClO(4))(2)·2C(3)H(7)NO, the Ag(I) atom is pentacoordinated by three N atoms from the tridentate chelating terpyridyl group and by one N atom and one O atom from the quinolin-8-yloxy group in a distorted square-pyramidal geometry with the O atom at the apical position. The centrosymmetric complex cation involves intramolecular π–π stacking interactions [centroid–centroid distance = 3.862 (4) Å] between the central pyridine and benzene rings. In the crystal structure, intermolecular C—H⋯O hydrogen bonds result in the formation of a supramolecular network. |
| format | Text |
| id | pubmed-2972071 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29720712010-12-30 Bis{μ-4′-[4-(quinolin-8-yloxymethyl)phenyl]-2,2′:6′,2′′-terpyridine}disilver(I) bis(perchlorate) dimethylformamide disolvate Chen, Chang-Juan Liu, Feng-Neng Zhang, Ai-Jiang Zhang, Liang-Wei Liu, Xiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the binuclear title complex, [Ag(2)(C(31)H(22)N(4)O)(2)](ClO(4))(2)·2C(3)H(7)NO, the Ag(I) atom is pentacoordinated by three N atoms from the tridentate chelating terpyridyl group and by one N atom and one O atom from the quinolin-8-yloxy group in a distorted square-pyramidal geometry with the O atom at the apical position. The centrosymmetric complex cation involves intramolecular π–π stacking interactions [centroid–centroid distance = 3.862 (4) Å] between the central pyridine and benzene rings. In the crystal structure, intermolecular C—H⋯O hydrogen bonds result in the formation of a supramolecular network. International Union of Crystallography 2009-11-25 /pmc/articles/PMC2972071/ /pubmed/21578682 http://dx.doi.org/10.1107/S1600536809046832 Text en © Chen et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Chen, Chang-Juan Liu, Feng-Neng Zhang, Ai-Jiang Zhang, Liang-Wei Liu, Xiang Bis{μ-4′-[4-(quinolin-8-yloxymethyl)phenyl]-2,2′:6′,2′′-terpyridine}disilver(I) bis(perchlorate) dimethylformamide disolvate |
| title | Bis{μ-4′-[4-(quinolin-8-yloxymethyl)phenyl]-2,2′:6′,2′′-terpyridine}disilver(I) bis(perchlorate) dimethylformamide disolvate |
| title_full | Bis{μ-4′-[4-(quinolin-8-yloxymethyl)phenyl]-2,2′:6′,2′′-terpyridine}disilver(I) bis(perchlorate) dimethylformamide disolvate |
| title_fullStr | Bis{μ-4′-[4-(quinolin-8-yloxymethyl)phenyl]-2,2′:6′,2′′-terpyridine}disilver(I) bis(perchlorate) dimethylformamide disolvate |
| title_full_unstemmed | Bis{μ-4′-[4-(quinolin-8-yloxymethyl)phenyl]-2,2′:6′,2′′-terpyridine}disilver(I) bis(perchlorate) dimethylformamide disolvate |
| title_short | Bis{μ-4′-[4-(quinolin-8-yloxymethyl)phenyl]-2,2′:6′,2′′-terpyridine}disilver(I) bis(perchlorate) dimethylformamide disolvate |
| title_sort | bis{μ-4′-[4-(quinolin-8-yloxymethyl)phenyl]-2,2′:6′,2′′-terpyridine}disilver(i) bis(perchlorate) dimethylformamide disolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972071/ https://www.ncbi.nlm.nih.gov/pubmed/21578682 http://dx.doi.org/10.1107/S1600536809046832 |
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