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Tris(methyl 3-oxobutanoato-κ(2) O,O′)aluminium(III)
In the title compound, [Al(C(5)H(7)O(3))(3)], three acac-type ligands (methyl 3-oxobutanoate anions) chelate to the aluminium(III) cation in a slightly distorted AlO(6) octahedral coordination geometry. Electron delocalization occurs within the chelating rings.
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972076/ https://www.ncbi.nlm.nih.gov/pubmed/21578687 http://dx.doi.org/10.1107/S1600536809049812 |
| _version_ | 1782190738578079744 |
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| author | Neelgund, Gururaj M. Shivashankar, S. A. Narasimhamurthy, T. Ng, Seik Weng |
| author_facet | Neelgund, Gururaj M. Shivashankar, S. A. Narasimhamurthy, T. Ng, Seik Weng |
| author_sort | Neelgund, Gururaj M. |
| collection | PubMed |
| description | In the title compound, [Al(C(5)H(7)O(3))(3)], three acac-type ligands (methyl 3-oxobutanoate anions) chelate to the aluminium(III) cation in a slightly distorted AlO(6) octahedral coordination geometry. Electron delocalization occurs within the chelating rings. |
| format | Text |
| id | pubmed-2972076 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29720762010-12-30 Tris(methyl 3-oxobutanoato-κ(2) O,O′)aluminium(III) Neelgund, Gururaj M. Shivashankar, S. A. Narasimhamurthy, T. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Al(C(5)H(7)O(3))(3)], three acac-type ligands (methyl 3-oxobutanoate anions) chelate to the aluminium(III) cation in a slightly distorted AlO(6) octahedral coordination geometry. Electron delocalization occurs within the chelating rings. International Union of Crystallography 2009-11-25 /pmc/articles/PMC2972076/ /pubmed/21578687 http://dx.doi.org/10.1107/S1600536809049812 Text en © Neelgund et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Neelgund, Gururaj M. Shivashankar, S. A. Narasimhamurthy, T. Ng, Seik Weng Tris(methyl 3-oxobutanoato-κ(2) O,O′)aluminium(III) |
| title | Tris(methyl 3-oxobutanoato-κ(2)
O,O′)aluminium(III) |
| title_full | Tris(methyl 3-oxobutanoato-κ(2)
O,O′)aluminium(III) |
| title_fullStr | Tris(methyl 3-oxobutanoato-κ(2)
O,O′)aluminium(III) |
| title_full_unstemmed | Tris(methyl 3-oxobutanoato-κ(2)
O,O′)aluminium(III) |
| title_short | Tris(methyl 3-oxobutanoato-κ(2)
O,O′)aluminium(III) |
| title_sort | tris(methyl 3-oxobutanoato-κ(2)
o,o′)aluminium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972076/ https://www.ncbi.nlm.nih.gov/pubmed/21578687 http://dx.doi.org/10.1107/S1600536809049812 |
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