catena-Poly[[bis­(dimethyl­formamide-κO)cadmium(II)]-di-μ(2)-dicyanamido-κ(4) N (1):N (5)]

In the title compound, [Cd(C(2)N(3))(2)(C(3)H(7)NO)(2)], the Cd(2+) ion lies on an inversion center and adopts an octa­hedral coordination geometry, in which four N atoms from four different dicyanamide ligands lie in the equatorial plane and two dimethyl­formamide O atoms occupy the axial positions...

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Detalles Bibliográficos
Autor principal: Zhang, Jinfang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972080/
https://www.ncbi.nlm.nih.gov/pubmed/21578589
http://dx.doi.org/10.1107/S1600536809046364
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author Zhang, Jinfang
author_facet Zhang, Jinfang
author_sort Zhang, Jinfang
collection PubMed
description In the title compound, [Cd(C(2)N(3))(2)(C(3)H(7)NO)(2)], the Cd(2+) ion lies on an inversion center and adopts an octa­hedral coordination geometry, in which four N atoms from four different dicyanamide ligands lie in the equatorial plane and two dimethyl­formamide O atoms occupy the axial positions. The Cd atoms are connected by two dicyanamide ligands, resulting in a neutral chain propagating parallel to [010].
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spelling pubmed-29720802010-12-30 catena-Poly[[bis­(dimethyl­formamide-κO)cadmium(II)]-di-μ(2)-dicyanamido-κ(4) N (1):N (5)] Zhang, Jinfang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(2)N(3))(2)(C(3)H(7)NO)(2)], the Cd(2+) ion lies on an inversion center and adopts an octa­hedral coordination geometry, in which four N atoms from four different dicyanamide ligands lie in the equatorial plane and two dimethyl­formamide O atoms occupy the axial positions. The Cd atoms are connected by two dicyanamide ligands, resulting in a neutral chain propagating parallel to [010]. International Union of Crystallography 2009-11-11 /pmc/articles/PMC2972080/ /pubmed/21578589 http://dx.doi.org/10.1107/S1600536809046364 Text en © Jinfang Zhang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Jinfang
catena-Poly[[bis­(dimethyl­formamide-κO)cadmium(II)]-di-μ(2)-dicyanamido-κ(4) N (1):N (5)]
title catena-Poly[[bis­(dimethyl­formamide-κO)cadmium(II)]-di-μ(2)-dicyanamido-κ(4) N (1):N (5)]
title_full catena-Poly[[bis­(dimethyl­formamide-κO)cadmium(II)]-di-μ(2)-dicyanamido-κ(4) N (1):N (5)]
title_fullStr catena-Poly[[bis­(dimethyl­formamide-κO)cadmium(II)]-di-μ(2)-dicyanamido-κ(4) N (1):N (5)]
title_full_unstemmed catena-Poly[[bis­(dimethyl­formamide-κO)cadmium(II)]-di-μ(2)-dicyanamido-κ(4) N (1):N (5)]
title_short catena-Poly[[bis­(dimethyl­formamide-κO)cadmium(II)]-di-μ(2)-dicyanamido-κ(4) N (1):N (5)]
title_sort catena-poly[[bis­(dimethyl­formamide-κo)cadmium(ii)]-di-μ(2)-dicyanamido-κ(4) n (1):n (5)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972080/
https://www.ncbi.nlm.nih.gov/pubmed/21578589
http://dx.doi.org/10.1107/S1600536809046364
work_keys_str_mv AT zhangjinfang catenapolybisdimethylformamidekocadmiumiidim2dicyanamidok4n1n5

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