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Di-μ(2)-bromido-bis[bromido(η(6)-1,2,4,5-tetramethylbenzene)ruthenium(II)]
The asymmetric unit of the title compound, [Ru(2)Br(4)(C(10)H(14))(2)], contains one half of the centrosymmetric molecule. Each Ru center is coordinated by tetramethylbenzene ring in a η(6)-coordination mode, and one terminal and two bridging bromine atoms. The aromatic rings and the Ru(2)Br(2) f...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972084/ https://www.ncbi.nlm.nih.gov/pubmed/21578690 http://dx.doi.org/10.1107/S1600536809049642 |
| _version_ | 1782190740482293760 |
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| author | Espinosa-Jalapa, Noel Hernández-Ortega, Simón Le Lagadec, Ronan Morales-Morales, David |
| author_facet | Espinosa-Jalapa, Noel Hernández-Ortega, Simón Le Lagadec, Ronan Morales-Morales, David |
| author_sort | Espinosa-Jalapa, Noel |
| collection | PubMed |
| description | The asymmetric unit of the title compound, [Ru(2)Br(4)(C(10)H(14))(2)], contains one half of the centrosymmetric molecule. Each Ru center is coordinated by tetramethylbenzene ring in a η(6)-coordination mode, and one terminal and two bridging bromine atoms. The aromatic rings and the Ru(2)Br(2) four-membered ring form a dihedral angle of 55.99 (8)°. In the crystal structure, weak intermolecular C—H⋯Br interactions link molecules into chains propagated in [001]. |
| format | Text |
| id | pubmed-2972084 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29720842010-12-30 Di-μ(2)-bromido-bis[bromido(η(6)-1,2,4,5-tetramethylbenzene)ruthenium(II)] Espinosa-Jalapa, Noel Hernández-Ortega, Simón Le Lagadec, Ronan Morales-Morales, David Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ru(2)Br(4)(C(10)H(14))(2)], contains one half of the centrosymmetric molecule. Each Ru center is coordinated by tetramethylbenzene ring in a η(6)-coordination mode, and one terminal and two bridging bromine atoms. The aromatic rings and the Ru(2)Br(2) four-membered ring form a dihedral angle of 55.99 (8)°. In the crystal structure, weak intermolecular C—H⋯Br interactions link molecules into chains propagated in [001]. International Union of Crystallography 2009-11-28 /pmc/articles/PMC2972084/ /pubmed/21578690 http://dx.doi.org/10.1107/S1600536809049642 Text en © Espinosa-Jalapa et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Espinosa-Jalapa, Noel Hernández-Ortega, Simón Le Lagadec, Ronan Morales-Morales, David Di-μ(2)-bromido-bis[bromido(η(6)-1,2,4,5-tetramethylbenzene)ruthenium(II)] |
| title | Di-μ(2)-bromido-bis[bromido(η(6)-1,2,4,5-tetramethylbenzene)ruthenium(II)] |
| title_full | Di-μ(2)-bromido-bis[bromido(η(6)-1,2,4,5-tetramethylbenzene)ruthenium(II)] |
| title_fullStr | Di-μ(2)-bromido-bis[bromido(η(6)-1,2,4,5-tetramethylbenzene)ruthenium(II)] |
| title_full_unstemmed | Di-μ(2)-bromido-bis[bromido(η(6)-1,2,4,5-tetramethylbenzene)ruthenium(II)] |
| title_short | Di-μ(2)-bromido-bis[bromido(η(6)-1,2,4,5-tetramethylbenzene)ruthenium(II)] |
| title_sort | di-μ(2)-bromido-bis[bromido(η(6)-1,2,4,5-tetramethylbenzene)ruthenium(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972084/ https://www.ncbi.nlm.nih.gov/pubmed/21578690 http://dx.doi.org/10.1107/S1600536809049642 |
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