2,4-Dibromo-6-{(E)-[(R)-1-phenyl­ethyl]imino­meth­yl}phenol

In the title Schiff base, C(15)H(13)Br(2)NO, the benzene and phenyl rings form a dihedral angle of 75.18 (13)°. The N=C bond length of 1.263 (6) Å is shorter than of the N—C bond [1.476 (5) Å], indicating a double bond. In the crystal, there is some pseudosymmetry. This occurs because most of the tw...

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Detalles Bibliográficos
Autores principales: Xia, Dong-Guo, Ye, Ya-Fen, Lei, Ke-Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972087/
https://www.ncbi.nlm.nih.gov/pubmed/21578884
http://dx.doi.org/10.1107/S1600536809044638
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author Xia, Dong-Guo
Ye, Ya-Fen
Lei, Ke-Wei
author_facet Xia, Dong-Guo
Ye, Ya-Fen
Lei, Ke-Wei
author_sort Xia, Dong-Guo
collection PubMed
description In the title Schiff base, C(15)H(13)Br(2)NO, the benzene and phenyl rings form a dihedral angle of 75.18 (13)°. The N=C bond length of 1.263 (6) Å is shorter than of the N—C bond [1.476 (5) Å], indicating a double bond. In the crystal, there is some pseudosymmetry. This occurs because most of the two mol­ecules are centrosymmetrically related. The mol­ecular structure is stabilized by intra­molecular O—H⋯N hydrogen bonds.
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spelling pubmed-29720872010-12-30 2,4-Dibromo-6-{(E)-[(R)-1-phenyl­ethyl]imino­meth­yl}phenol Xia, Dong-Guo Ye, Ya-Fen Lei, Ke-Wei Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title Schiff base, C(15)H(13)Br(2)NO, the benzene and phenyl rings form a dihedral angle of 75.18 (13)°. The N=C bond length of 1.263 (6) Å is shorter than of the N—C bond [1.476 (5) Å], indicating a double bond. In the crystal, there is some pseudosymmetry. This occurs because most of the two mol­ecules are centrosymmetrically related. The mol­ecular structure is stabilized by intra­molecular O—H⋯N hydrogen bonds. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2972087/ /pubmed/21578884 http://dx.doi.org/10.1107/S1600536809044638 Text en © Xia et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Xia, Dong-Guo
Ye, Ya-Fen
Lei, Ke-Wei
2,4-Dibromo-6-{(E)-[(R)-1-phenyl­ethyl]imino­meth­yl}phenol
title 2,4-Dibromo-6-{(E)-[(R)-1-phenyl­ethyl]imino­meth­yl}phenol
title_full 2,4-Dibromo-6-{(E)-[(R)-1-phenyl­ethyl]imino­meth­yl}phenol
title_fullStr 2,4-Dibromo-6-{(E)-[(R)-1-phenyl­ethyl]imino­meth­yl}phenol
title_full_unstemmed 2,4-Dibromo-6-{(E)-[(R)-1-phenyl­ethyl]imino­meth­yl}phenol
title_short 2,4-Dibromo-6-{(E)-[(R)-1-phenyl­ethyl]imino­meth­yl}phenol
title_sort 2,4-dibromo-6-{(e)-[(r)-1-phenyl­ethyl]imino­meth­yl}phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972087/
https://www.ncbi.nlm.nih.gov/pubmed/21578884
http://dx.doi.org/10.1107/S1600536809044638
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