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(Benzoato-κO)(benzoic acid-κO)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)hydroxidocopper(II) monohydrate
In the structure of the title complex, [Cu(C(7)H(5)O(2))(OH)(C(12)H(12)N(2))(C(7)H(6)O(2))]·H(2)O, the Cu(II) ion is pentacoordinated in a tetragonal-pyramidal geometry with one O atom of a hydroxide group, one O atom of a benzoate anion and two N atoms of a 4,4′-dimethyl-2,2′-bipyridine ligand oc...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972094/ https://www.ncbi.nlm.nih.gov/pubmed/21578575 http://dx.doi.org/10.1107/S1600536809043189 |
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author | Yao, Li Li, Wen-Juan |
author_facet | Yao, Li Li, Wen-Juan |
author_sort | Yao, Li |
collection | PubMed |
description | In the structure of the title complex, [Cu(C(7)H(5)O(2))(OH)(C(12)H(12)N(2))(C(7)H(6)O(2))]·H(2)O, the Cu(II) ion is pentacoordinated in a tetragonal-pyramidal geometry with one O atom of a hydroxide group, one O atom of a benzoate anion and two N atoms of a 4,4′-dimethyl-2,2′-bipyridine ligand occupying the basal plane, and one O atom of a benzoic acid molecule located at the apical site. The title complex was refined with a metal-coordinated OH group and a ‘free’ benzoic acid molecule, although it can be assumed that the proton is delocalized between the OH and the COOH group. The uncoordinated water molecule is equally disordered over two positions. The structure displays O—H⋯O hydrogen bonding. |
format | Text |
id | pubmed-2972094 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29720942010-12-30 (Benzoato-κO)(benzoic acid-κO)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)hydroxidocopper(II) monohydrate Yao, Li Li, Wen-Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title complex, [Cu(C(7)H(5)O(2))(OH)(C(12)H(12)N(2))(C(7)H(6)O(2))]·H(2)O, the Cu(II) ion is pentacoordinated in a tetragonal-pyramidal geometry with one O atom of a hydroxide group, one O atom of a benzoate anion and two N atoms of a 4,4′-dimethyl-2,2′-bipyridine ligand occupying the basal plane, and one O atom of a benzoic acid molecule located at the apical site. The title complex was refined with a metal-coordinated OH group and a ‘free’ benzoic acid molecule, although it can be assumed that the proton is delocalized between the OH and the COOH group. The uncoordinated water molecule is equally disordered over two positions. The structure displays O—H⋯O hydrogen bonding. International Union of Crystallography 2009-11-07 /pmc/articles/PMC2972094/ /pubmed/21578575 http://dx.doi.org/10.1107/S1600536809043189 Text en © Yao and Li 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yao, Li Li, Wen-Juan (Benzoato-κO)(benzoic acid-κO)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)hydroxidocopper(II) monohydrate |
title | (Benzoato-κO)(benzoic acid-κO)(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)hydroxidocopper(II) monohydrate |
title_full | (Benzoato-κO)(benzoic acid-κO)(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)hydroxidocopper(II) monohydrate |
title_fullStr | (Benzoato-κO)(benzoic acid-κO)(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)hydroxidocopper(II) monohydrate |
title_full_unstemmed | (Benzoato-κO)(benzoic acid-κO)(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)hydroxidocopper(II) monohydrate |
title_short | (Benzoato-κO)(benzoic acid-κO)(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)hydroxidocopper(II) monohydrate |
title_sort | (benzoato-κo)(benzoic acid-κo)(4,4′-dimethyl-2,2′-bipyridine-κ(2)
n,n′)hydroxidocopper(ii) monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972094/ https://www.ncbi.nlm.nih.gov/pubmed/21578575 http://dx.doi.org/10.1107/S1600536809043189 |
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