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(Benzoato-κO)(benzoic acid-κO)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)hydroxidocopper(II) monohydrate

In the structure of the title complex, [Cu(C(7)H(5)O(2))(OH)(C(12)H(12)N(2))(C(7)H(6)O(2))]·H(2)O, the Cu(II) ion is penta­coordinated in a tetra­gonal-pyramidal geometry with one O atom of a hydroxide group, one O atom of a benzoate anion and two N atoms of a 4,4′-dimethyl-2,2′-bipyridine ligand oc...

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Detalles Bibliográficos
Autores principales: Yao, Li, Li, Wen-Juan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972094/
https://www.ncbi.nlm.nih.gov/pubmed/21578575
http://dx.doi.org/10.1107/S1600536809043189
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author Yao, Li
Li, Wen-Juan
author_facet Yao, Li
Li, Wen-Juan
author_sort Yao, Li
collection PubMed
description In the structure of the title complex, [Cu(C(7)H(5)O(2))(OH)(C(12)H(12)N(2))(C(7)H(6)O(2))]·H(2)O, the Cu(II) ion is penta­coordinated in a tetra­gonal-pyramidal geometry with one O atom of a hydroxide group, one O atom of a benzoate anion and two N atoms of a 4,4′-dimethyl-2,2′-bipyridine ligand occupying the basal plane, and one O atom of a benzoic acid mol­ecule located at the apical site. The title complex was refined with a metal-coordinated OH group and a ‘free’ benzoic acid molecule, although it can be assumed that the proton is delocalized between the OH and the COOH group. The uncoordinated water mol­ecule is equally disordered over two positions. The structure displays O—H⋯O hydrogen bonding.
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spelling pubmed-29720942010-12-30 (Benzoato-κO)(benzoic acid-κO)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)hydroxidocopper(II) monohydrate Yao, Li Li, Wen-Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title complex, [Cu(C(7)H(5)O(2))(OH)(C(12)H(12)N(2))(C(7)H(6)O(2))]·H(2)O, the Cu(II) ion is penta­coordinated in a tetra­gonal-pyramidal geometry with one O atom of a hydroxide group, one O atom of a benzoate anion and two N atoms of a 4,4′-dimethyl-2,2′-bipyridine ligand occupying the basal plane, and one O atom of a benzoic acid mol­ecule located at the apical site. The title complex was refined with a metal-coordinated OH group and a ‘free’ benzoic acid molecule, although it can be assumed that the proton is delocalized between the OH and the COOH group. The uncoordinated water mol­ecule is equally disordered over two positions. The structure displays O—H⋯O hydrogen bonding. International Union of Crystallography 2009-11-07 /pmc/articles/PMC2972094/ /pubmed/21578575 http://dx.doi.org/10.1107/S1600536809043189 Text en © Yao and Li 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yao, Li
Li, Wen-Juan
(Benzoato-κO)(benzoic acid-κO)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)hydroxidocopper(II) monohydrate
title (Benzoato-κO)(benzoic acid-κO)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)hydroxidocopper(II) monohydrate
title_full (Benzoato-κO)(benzoic acid-κO)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)hydroxidocopper(II) monohydrate
title_fullStr (Benzoato-κO)(benzoic acid-κO)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)hydroxidocopper(II) monohydrate
title_full_unstemmed (Benzoato-κO)(benzoic acid-κO)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)hydroxidocopper(II) monohydrate
title_short (Benzoato-κO)(benzoic acid-κO)(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)hydroxidocopper(II) monohydrate
title_sort (benzoato-κo)(benzoic acid-κo)(4,4′-dimethyl-2,2′-bipyridine-κ(2) n,n′)hydroxidocopper(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972094/
https://www.ncbi.nlm.nih.gov/pubmed/21578575
http://dx.doi.org/10.1107/S1600536809043189
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