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catena-Poly[[diaquazinc(II)]-μ-piperazine-1,4-diacetato-κ(4) N (1),O (1):N (4),O (4)]
The asymmetric unit of the title compound, [Zn(C(8)H(12)N(2)O(4))(H(2)O)(2)](n), contains a Zn(II) ion residing on an inversion center, half of a centrosymmetric piperazine-1,4-diacetate ligand (L) and a water molecule. The Zn(II) ion is trans-coordinated by two N,O-bidentate L ligands and by two w...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972100/ https://www.ncbi.nlm.nih.gov/pubmed/21578597 http://dx.doi.org/10.1107/S1600536809045462 |
Sumario: | The asymmetric unit of the title compound, [Zn(C(8)H(12)N(2)O(4))(H(2)O)(2)](n), contains a Zn(II) ion residing on an inversion center, half of a centrosymmetric piperazine-1,4-diacetate ligand (L) and a water molecule. The Zn(II) ion is trans-coordinated by two N,O-bidentate L ligands and by two water molecules in a distorted octahedral geometry. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link polymeric chains into a three-dimensional supramolecular structure. |
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