catena-Poly[[diaqua­zinc(II)]-μ-piper­azine-1,4-diacetato-κ(4) N (1),O (1):N (4),O (4)]

The asymmetric unit of the title compound, [Zn(C(8)H(12)N(2)O(4))(H(2)O)(2)](n), contains a Zn(II) ion residing on an inversion center, half of a centrosymmetric piperazine-1,4-diacetate ligand (L) and a water mol­ecule. The Zn(II) ion is trans-coordinated by two N,O-bidentate L ligands and by two w...

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Detalles Bibliográficos
Autor principal: Bi, Jian-Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972100/
https://www.ncbi.nlm.nih.gov/pubmed/21578597
http://dx.doi.org/10.1107/S1600536809045462
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author Bi, Jian-Hong
author_facet Bi, Jian-Hong
author_sort Bi, Jian-Hong
collection PubMed
description The asymmetric unit of the title compound, [Zn(C(8)H(12)N(2)O(4))(H(2)O)(2)](n), contains a Zn(II) ion residing on an inversion center, half of a centrosymmetric piperazine-1,4-diacetate ligand (L) and a water mol­ecule. The Zn(II) ion is trans-coordinated by two N,O-bidentate L ligands and by two water mol­ecules in a distorted octa­hedral geometry. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link polymeric chains into a three-dimensional supra­molecular structure.
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spelling pubmed-29721002010-12-30 catena-Poly[[diaqua­zinc(II)]-μ-piper­azine-1,4-diacetato-κ(4) N (1),O (1):N (4),O (4)] Bi, Jian-Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Zn(C(8)H(12)N(2)O(4))(H(2)O)(2)](n), contains a Zn(II) ion residing on an inversion center, half of a centrosymmetric piperazine-1,4-diacetate ligand (L) and a water mol­ecule. The Zn(II) ion is trans-coordinated by two N,O-bidentate L ligands and by two water mol­ecules in a distorted octa­hedral geometry. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link polymeric chains into a three-dimensional supra­molecular structure. International Union of Crystallography 2009-11-11 /pmc/articles/PMC2972100/ /pubmed/21578597 http://dx.doi.org/10.1107/S1600536809045462 Text en © Jian-Hong Bi 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bi, Jian-Hong
catena-Poly[[diaqua­zinc(II)]-μ-piper­azine-1,4-diacetato-κ(4) N (1),O (1):N (4),O (4)]
title catena-Poly[[diaqua­zinc(II)]-μ-piper­azine-1,4-diacetato-κ(4) N (1),O (1):N (4),O (4)]
title_full catena-Poly[[diaqua­zinc(II)]-μ-piper­azine-1,4-diacetato-κ(4) N (1),O (1):N (4),O (4)]
title_fullStr catena-Poly[[diaqua­zinc(II)]-μ-piper­azine-1,4-diacetato-κ(4) N (1),O (1):N (4),O (4)]
title_full_unstemmed catena-Poly[[diaqua­zinc(II)]-μ-piper­azine-1,4-diacetato-κ(4) N (1),O (1):N (4),O (4)]
title_short catena-Poly[[diaqua­zinc(II)]-μ-piper­azine-1,4-diacetato-κ(4) N (1),O (1):N (4),O (4)]
title_sort catena-poly[[diaqua­zinc(ii)]-μ-piper­azine-1,4-diacetato-κ(4) n (1),o (1):n (4),o (4)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972100/
https://www.ncbi.nlm.nih.gov/pubmed/21578597
http://dx.doi.org/10.1107/S1600536809045462
work_keys_str_mv AT bijianhong catenapolydiaquazinciimpiperazine14diacetatok4n1o1n4o4

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