Cargando…
Bis(4-aminobenzenesulfonato-κO)bis(propane-1,3-diamine-κ(2) N,N′)copper(II) dihydrate
In the title compound, [Cu(C(3)H(10)N(2))(2)(C(6)H(6)NO(3)S)(2)]·2H(2)O, the Cu(II) atom lies on an inversion center and is hexacoordinated by four N atoms from two 1,3-diaminopropane ligands and two O atoms from two 4-aminobenzenesulfonate ligands in a trans arrangement, displaying a distorted...
| Autores principales: | , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972104/ https://www.ncbi.nlm.nih.gov/pubmed/21578685 http://dx.doi.org/10.1107/S1600536809049769 |
| _version_ | 1782190745294209024 |
|---|---|
| author | Zhang, Ke-Juan Meng, Xiang-Gao Li, Xiu-Ling |
| author_facet | Zhang, Ke-Juan Meng, Xiang-Gao Li, Xiu-Ling |
| author_sort | Zhang, Ke-Juan |
| collection | PubMed |
| description | In the title compound, [Cu(C(3)H(10)N(2))(2)(C(6)H(6)NO(3)S)(2)]·2H(2)O, the Cu(II) atom lies on an inversion center and is hexacoordinated by four N atoms from two 1,3-diaminopropane ligands and two O atoms from two 4-aminobenzenesulfonate ligands in a trans arrangement, displaying a distorted and axially elongated octahedral coordination geometry, with the O atoms at the axial positions. A three-dimensional network is formed in the crystal structure through O—H⋯O, N—H⋯O and N—H⋯N hydrogen bonds. |
| format | Text |
| id | pubmed-2972104 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29721042010-12-30 Bis(4-aminobenzenesulfonato-κO)bis(propane-1,3-diamine-κ(2) N,N′)copper(II) dihydrate Zhang, Ke-Juan Meng, Xiang-Gao Li, Xiu-Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(3)H(10)N(2))(2)(C(6)H(6)NO(3)S)(2)]·2H(2)O, the Cu(II) atom lies on an inversion center and is hexacoordinated by four N atoms from two 1,3-diaminopropane ligands and two O atoms from two 4-aminobenzenesulfonate ligands in a trans arrangement, displaying a distorted and axially elongated octahedral coordination geometry, with the O atoms at the axial positions. A three-dimensional network is formed in the crystal structure through O—H⋯O, N—H⋯O and N—H⋯N hydrogen bonds. International Union of Crystallography 2009-11-25 /pmc/articles/PMC2972104/ /pubmed/21578685 http://dx.doi.org/10.1107/S1600536809049769 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhang, Ke-Juan Meng, Xiang-Gao Li, Xiu-Ling Bis(4-aminobenzenesulfonato-κO)bis(propane-1,3-diamine-κ(2) N,N′)copper(II) dihydrate |
| title | Bis(4-aminobenzenesulfonato-κO)bis(propane-1,3-diamine-κ(2)
N,N′)copper(II) dihydrate |
| title_full | Bis(4-aminobenzenesulfonato-κO)bis(propane-1,3-diamine-κ(2)
N,N′)copper(II) dihydrate |
| title_fullStr | Bis(4-aminobenzenesulfonato-κO)bis(propane-1,3-diamine-κ(2)
N,N′)copper(II) dihydrate |
| title_full_unstemmed | Bis(4-aminobenzenesulfonato-κO)bis(propane-1,3-diamine-κ(2)
N,N′)copper(II) dihydrate |
| title_short | Bis(4-aminobenzenesulfonato-κO)bis(propane-1,3-diamine-κ(2)
N,N′)copper(II) dihydrate |
| title_sort | bis(4-aminobenzenesulfonato-κo)bis(propane-1,3-diamine-κ(2)
n,n′)copper(ii) dihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972104/ https://www.ncbi.nlm.nih.gov/pubmed/21578685 http://dx.doi.org/10.1107/S1600536809049769 |
| work_keys_str_mv | AT zhangkejuan bis4aminobenzenesulfonatokobispropane13diaminek2nncopperiidihydrate AT mengxianggao bis4aminobenzenesulfonatokobispropane13diaminek2nncopperiidihydrate AT lixiuling bis4aminobenzenesulfonatokobispropane13diaminek2nncopperiidihydrate |