Tris{2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolate-κ(2) O,O′}tris­(thio­cyanato-κN)europium(III)

The metal center in the structure of the title compound, [Eu(NCS)(3)(C(15)H(15)NO(2))(3)], is coordinated by three Schiff base 2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolate (L) ligands and three independent thio­cyanate ions. In the crystal structure, the acidic H atom is located on the Sc...

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Detalles Bibliográficos
Autores principales: Liu, Jian-Feng, Liu, Jia-Lu, Zhao, Guo-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972108/
https://www.ncbi.nlm.nih.gov/pubmed/21578663
http://dx.doi.org/10.1107/S1600536809049125
Descripción
Sumario:The metal center in the structure of the title compound, [Eu(NCS)(3)(C(15)H(15)NO(2))(3)], is coordinated by three Schiff base 2-meth­oxy-6-[(4-methyl­phen­yl)iminiometh­yl]phenolate (L) ligands and three independent thio­cyanate ions. In the crystal structure, the acidic H atom is located on the Schiff base N atom and hydrogen bonded to the phenolate O atom. The coordination environment of the Eu(III) ion is nine-coordinate by three chelating methoxy­phenolate pairs of O atoms and three N-atom terminals of the thio­cyanate ions. The compound is isostructural with the Ce(III) analogue [Liu et al. (2009 ▶). Acta Cryst. E65, m650].

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