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Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ(2) O,O′}tris(thiocyanato-κN)europium(III)
The metal center in the structure of the title compound, [Eu(NCS)(3)(C(15)H(15)NO(2))(3)], is coordinated by three Schiff base 2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate (L) ligands and three independent thiocyanate ions. In the crystal structure, the acidic H atom is located on the Sc...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972108/ https://www.ncbi.nlm.nih.gov/pubmed/21578663 http://dx.doi.org/10.1107/S1600536809049125 |
| _version_ | 1782190746213810176 |
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| author | Liu, Jian-Feng Liu, Jia-Lu Zhao, Guo-Liang |
| author_facet | Liu, Jian-Feng Liu, Jia-Lu Zhao, Guo-Liang |
| author_sort | Liu, Jian-Feng |
| collection | PubMed |
| description | The metal center in the structure of the title compound, [Eu(NCS)(3)(C(15)H(15)NO(2))(3)], is coordinated by three Schiff base 2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate (L) ligands and three independent thiocyanate ions. In the crystal structure, the acidic H atom is located on the Schiff base N atom and hydrogen bonded to the phenolate O atom. The coordination environment of the Eu(III) ion is nine-coordinate by three chelating methoxyphenolate pairs of O atoms and three N-atom terminals of the thiocyanate ions. The compound is isostructural with the Ce(III) analogue [Liu et al. (2009 ▶). Acta Cryst. E65, m650]. |
| format | Text |
| id | pubmed-2972108 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29721082010-12-30 Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ(2) O,O′}tris(thiocyanato-κN)europium(III) Liu, Jian-Feng Liu, Jia-Lu Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The metal center in the structure of the title compound, [Eu(NCS)(3)(C(15)H(15)NO(2))(3)], is coordinated by three Schiff base 2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate (L) ligands and three independent thiocyanate ions. In the crystal structure, the acidic H atom is located on the Schiff base N atom and hydrogen bonded to the phenolate O atom. The coordination environment of the Eu(III) ion is nine-coordinate by three chelating methoxyphenolate pairs of O atoms and three N-atom terminals of the thiocyanate ions. The compound is isostructural with the Ce(III) analogue [Liu et al. (2009 ▶). Acta Cryst. E65, m650]. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2972108/ /pubmed/21578663 http://dx.doi.org/10.1107/S1600536809049125 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Jian-Feng Liu, Jia-Lu Zhao, Guo-Liang Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ(2) O,O′}tris(thiocyanato-κN)europium(III) |
| title | Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ(2)
O,O′}tris(thiocyanato-κN)europium(III) |
| title_full | Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ(2)
O,O′}tris(thiocyanato-κN)europium(III) |
| title_fullStr | Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ(2)
O,O′}tris(thiocyanato-κN)europium(III) |
| title_full_unstemmed | Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ(2)
O,O′}tris(thiocyanato-κN)europium(III) |
| title_short | Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ(2)
O,O′}tris(thiocyanato-κN)europium(III) |
| title_sort | tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ(2)
o,o′}tris(thiocyanato-κn)europium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972108/ https://www.ncbi.nlm.nih.gov/pubmed/21578663 http://dx.doi.org/10.1107/S1600536809049125 |
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