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Tetraaquabis[3-(4-pyridyl)benzoato-κN]nickel(II)
The Ni(II) atom in the title compound, [Ni(C(12)H(8)NO(2))(2)(H(2)O)(4)], exists in an all-trans octahedral coordination environment. The 3-(4-pyridyl)benzoate ligand binds to Ni atom through the pyridyl N atom; the pyridine and benzene rings are oriented at a dihedral angle of 26.27 (10)°. Adjace...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972113/ https://www.ncbi.nlm.nih.gov/pubmed/21578709 http://dx.doi.org/10.1107/S1600536809051204 |
| _version_ | 1782190747418624000 |
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| author | Wang, Qiang-Xin Zeng, Ming-Hua Ng, Seik Weng |
| author_facet | Wang, Qiang-Xin Zeng, Ming-Hua Ng, Seik Weng |
| author_sort | Wang, Qiang-Xin |
| collection | PubMed |
| description | The Ni(II) atom in the title compound, [Ni(C(12)H(8)NO(2))(2)(H(2)O)(4)], exists in an all-trans octahedral coordination environment. The 3-(4-pyridyl)benzoate ligand binds to Ni atom through the pyridyl N atom; the pyridine and benzene rings are oriented at a dihedral angle of 26.27 (10)°. Adjacent complexes are linked by O—H⋯O hydrogen bonds, forming a three-dimensional network. The metal atom lies on a special position of 2 site symmetry in the crystal structure. |
| format | Text |
| id | pubmed-2972113 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29721132010-12-30 Tetraaquabis[3-(4-pyridyl)benzoato-κN]nickel(II) Wang, Qiang-Xin Zeng, Ming-Hua Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ni(II) atom in the title compound, [Ni(C(12)H(8)NO(2))(2)(H(2)O)(4)], exists in an all-trans octahedral coordination environment. The 3-(4-pyridyl)benzoate ligand binds to Ni atom through the pyridyl N atom; the pyridine and benzene rings are oriented at a dihedral angle of 26.27 (10)°. Adjacent complexes are linked by O—H⋯O hydrogen bonds, forming a three-dimensional network. The metal atom lies on a special position of 2 site symmetry in the crystal structure. International Union of Crystallography 2009-11-28 /pmc/articles/PMC2972113/ /pubmed/21578709 http://dx.doi.org/10.1107/S1600536809051204 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Qiang-Xin Zeng, Ming-Hua Ng, Seik Weng Tetraaquabis[3-(4-pyridyl)benzoato-κN]nickel(II) |
| title | Tetraaquabis[3-(4-pyridyl)benzoato-κN]nickel(II) |
| title_full | Tetraaquabis[3-(4-pyridyl)benzoato-κN]nickel(II) |
| title_fullStr | Tetraaquabis[3-(4-pyridyl)benzoato-κN]nickel(II) |
| title_full_unstemmed | Tetraaquabis[3-(4-pyridyl)benzoato-κN]nickel(II) |
| title_short | Tetraaquabis[3-(4-pyridyl)benzoato-κN]nickel(II) |
| title_sort | tetraaquabis[3-(4-pyridyl)benzoato-κn]nickel(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972113/ https://www.ncbi.nlm.nih.gov/pubmed/21578709 http://dx.doi.org/10.1107/S1600536809051204 |
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