A new hybrid Dawson-type molybdenum arsenate derivative: (H(2)bpy)(3)[As(2)Mo(18)O(62)] (bpy = 4,4′-bipyridine)

The title compound, tris­(4,4′-bipyridinium) diarsenoocta­deca­molybdate(VI), (C(10)H(10)N(2))(3)[As(2)Mo(18)O(62)], featuring protonated bipyridine mol­ecules and a classical Dawson-type polyoxo-anion, has been synthesized under hydro­thermal conditions. The polyoxoanions are linked together via th...

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Detalles Bibliográficos
Autores principales: Yu, Hai-hui, Zhang, Xiao, Kong, Li, Xu, Ji-qing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972115/
https://www.ncbi.nlm.nih.gov/pubmed/21578702
http://dx.doi.org/10.1107/S1600536809050260
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author Yu, Hai-hui
Zhang, Xiao
Kong, Li
Xu, Ji-qing
author_facet Yu, Hai-hui
Zhang, Xiao
Kong, Li
Xu, Ji-qing
author_sort Yu, Hai-hui
collection PubMed
description The title compound, tris­(4,4′-bipyridinium) diarsenoocta­deca­molybdate(VI), (C(10)H(10)N(2))(3)[As(2)Mo(18)O(62)], featuring protonated bipyridine mol­ecules and a classical Dawson-type polyoxo-anion, has been synthesized under hydro­thermal conditions. The polyoxoanions are linked together via the bipyridyl cations, acting as hydrogen-bond donors, generating a two-dimensional supra­molecular network. The asymmetric unit contains 1.5 4,4′-bipyridinium (H(2)bpy) units, with an inversion centre in the central bond of the second H(2)bpy unit. The site symmetry of the anion is [Image: see text].
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spelling pubmed-29721152010-12-30 A new hybrid Dawson-type molybdenum arsenate derivative: (H(2)bpy)(3)[As(2)Mo(18)O(62)] (bpy = 4,4′-bipyridine) Yu, Hai-hui Zhang, Xiao Kong, Li Xu, Ji-qing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, tris­(4,4′-bipyridinium) diarsenoocta­deca­molybdate(VI), (C(10)H(10)N(2))(3)[As(2)Mo(18)O(62)], featuring protonated bipyridine mol­ecules and a classical Dawson-type polyoxo-anion, has been synthesized under hydro­thermal conditions. The polyoxoanions are linked together via the bipyridyl cations, acting as hydrogen-bond donors, generating a two-dimensional supra­molecular network. The asymmetric unit contains 1.5 4,4′-bipyridinium (H(2)bpy) units, with an inversion centre in the central bond of the second H(2)bpy unit. The site symmetry of the anion is [Image: see text]. International Union of Crystallography 2009-11-28 /pmc/articles/PMC2972115/ /pubmed/21578702 http://dx.doi.org/10.1107/S1600536809050260 Text en © Yu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yu, Hai-hui
Zhang, Xiao
Kong, Li
Xu, Ji-qing
A new hybrid Dawson-type molybdenum arsenate derivative: (H(2)bpy)(3)[As(2)Mo(18)O(62)] (bpy = 4,4′-bipyridine)
title A new hybrid Dawson-type molybdenum arsenate derivative: (H(2)bpy)(3)[As(2)Mo(18)O(62)] (bpy = 4,4′-bipyridine)
title_full A new hybrid Dawson-type molybdenum arsenate derivative: (H(2)bpy)(3)[As(2)Mo(18)O(62)] (bpy = 4,4′-bipyridine)
title_fullStr A new hybrid Dawson-type molybdenum arsenate derivative: (H(2)bpy)(3)[As(2)Mo(18)O(62)] (bpy = 4,4′-bipyridine)
title_full_unstemmed A new hybrid Dawson-type molybdenum arsenate derivative: (H(2)bpy)(3)[As(2)Mo(18)O(62)] (bpy = 4,4′-bipyridine)
title_short A new hybrid Dawson-type molybdenum arsenate derivative: (H(2)bpy)(3)[As(2)Mo(18)O(62)] (bpy = 4,4′-bipyridine)
title_sort new hybrid dawson-type molybdenum arsenate derivative: (h(2)bpy)(3)[as(2)mo(18)o(62)] (bpy = 4,4′-bipyridine)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972115/
https://www.ncbi.nlm.nih.gov/pubmed/21578702
http://dx.doi.org/10.1107/S1600536809050260
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