N,N-Bis(diphenyl­phosphino)ethyl­amine

In the title compound, C(26)H(25)NP(2), the diphenyl­phosphino groups are staggered relative to the PNP backbone, even though the ethyl substituent coordinated to the N atom is not sterically bulky. The N atom adapts an almost planar geometry with two P atoms and a C atom of the allyl group attached...

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Detalles Bibliográficos
Autores principales: Cloete, Nicoline, Visser, Hendrik G., Roodt, Andreas, Gabrielli, William F.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972116/
https://www.ncbi.nlm.nih.gov/pubmed/21578811
http://dx.doi.org/10.1107/S1600536809045978
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author Cloete, Nicoline
Visser, Hendrik G.
Roodt, Andreas
Gabrielli, William F.
author_facet Cloete, Nicoline
Visser, Hendrik G.
Roodt, Andreas
Gabrielli, William F.
author_sort Cloete, Nicoline
collection PubMed
description In the title compound, C(26)H(25)NP(2), the diphenyl­phosphino groups are staggered relative to the PNP backbone, even though the ethyl substituent coordinated to the N atom is not sterically bulky. The N atom adapts an almost planar geometry with two P atoms and a C atom of the allyl group attached to it in order to accommodate the steric bulk of the phenyl groups and the alkyl group. The distortion of the trigonal-pyramidal geometry of the nitro­gen is further illustrated by the bond angles which range between 114.0 (1) and 123.7 (1)°. There are no classical inter­molecular inter­actions.
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spelling pubmed-29721162010-12-30 N,N-Bis(diphenyl­phosphino)ethyl­amine Cloete, Nicoline Visser, Hendrik G. Roodt, Andreas Gabrielli, William F. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(25)NP(2), the diphenyl­phosphino groups are staggered relative to the PNP backbone, even though the ethyl substituent coordinated to the N atom is not sterically bulky. The N atom adapts an almost planar geometry with two P atoms and a C atom of the allyl group attached to it in order to accommodate the steric bulk of the phenyl groups and the alkyl group. The distortion of the trigonal-pyramidal geometry of the nitro­gen is further illustrated by the bond angles which range between 114.0 (1) and 123.7 (1)°. There are no classical inter­molecular inter­actions. International Union of Crystallography 2009-11-14 /pmc/articles/PMC2972116/ /pubmed/21578811 http://dx.doi.org/10.1107/S1600536809045978 Text en © Cloete et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cloete, Nicoline
Visser, Hendrik G.
Roodt, Andreas
Gabrielli, William F.
N,N-Bis(diphenyl­phosphino)ethyl­amine
title N,N-Bis(diphenyl­phosphino)ethyl­amine
title_full N,N-Bis(diphenyl­phosphino)ethyl­amine
title_fullStr N,N-Bis(diphenyl­phosphino)ethyl­amine
title_full_unstemmed N,N-Bis(diphenyl­phosphino)ethyl­amine
title_short N,N-Bis(diphenyl­phosphino)ethyl­amine
title_sort n,n-bis(diphenyl­phosphino)ethyl­amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972116/
https://www.ncbi.nlm.nih.gov/pubmed/21578811
http://dx.doi.org/10.1107/S1600536809045978
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AT gabrielliwilliamf nnbisdiphenylphosphinoethylamine

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