Methanol{2-meth­oxy-6-[(2-oxidoprop­yl)imino­meth­yl]phenolato}dioxidomolyb­denum(VI)

In the structure of the title compound, [Mo(C(11)H(13)NO(3))O(2)(CH(3)OH)], the Mo(VI) ion is octahedrally coordinated by two oxide O atoms, the N atom and two deprotonated OH groups of the tridentate Schiff base ligand 2-meth­oxy-6-[(2-oxidoprop­yl)imino­meth­yl]phenolate and by a methanol O atom....

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Detalles Bibliográficos
Autores principales: Saeednia, Samira, Sheikhshoaie, Iran, Stoeckli-Evans, Helen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972118/
https://www.ncbi.nlm.nih.gov/pubmed/21578621
http://dx.doi.org/10.1107/S1600536809047485
Descripción
Sumario:In the structure of the title compound, [Mo(C(11)H(13)NO(3))O(2)(CH(3)OH)], the Mo(VI) ion is octahedrally coordinated by two oxide O atoms, the N atom and two deprotonated OH groups of the tridentate Schiff base ligand 2-meth­oxy-6-[(2-oxidoprop­yl)imino­meth­yl]phenolate and by a methanol O atom. In the crystal structure, two complexes are linked via O—H⋯O hydrogen bonds, yielding a centrosymmetric arrangement involving the methanol hydr­oxy group and one of the ligand O atoms coordinated to the Mo(VI) ion.

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