Methanol{2-meth­oxy-6-[(2-oxidoprop­yl)imino­meth­yl]phenolato}dioxidomolyb­denum(VI)

In the structure of the title compound, [Mo(C(11)H(13)NO(3))O(2)(CH(3)OH)], the Mo(VI) ion is octahedrally coordinated by two oxide O atoms, the N atom and two deprotonated OH groups of the tridentate Schiff base ligand 2-meth­oxy-6-[(2-oxidoprop­yl)imino­meth­yl]phenolate and by a methanol O atom....

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Detalles Bibliográficos
Autores principales: Saeednia, Samira, Sheikhshoaie, Iran, Stoeckli-Evans, Helen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972118/
https://www.ncbi.nlm.nih.gov/pubmed/21578621
http://dx.doi.org/10.1107/S1600536809047485
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author Saeednia, Samira
Sheikhshoaie, Iran
Stoeckli-Evans, Helen
author_facet Saeednia, Samira
Sheikhshoaie, Iran
Stoeckli-Evans, Helen
author_sort Saeednia, Samira
collection PubMed
description In the structure of the title compound, [Mo(C(11)H(13)NO(3))O(2)(CH(3)OH)], the Mo(VI) ion is octahedrally coordinated by two oxide O atoms, the N atom and two deprotonated OH groups of the tridentate Schiff base ligand 2-meth­oxy-6-[(2-oxidoprop­yl)imino­meth­yl]phenolate and by a methanol O atom. In the crystal structure, two complexes are linked via O—H⋯O hydrogen bonds, yielding a centrosymmetric arrangement involving the methanol hydr­oxy group and one of the ligand O atoms coordinated to the Mo(VI) ion.
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spelling pubmed-29721182010-12-30 Methanol{2-meth­oxy-6-[(2-oxidoprop­yl)imino­meth­yl]phenolato}dioxidomolyb­denum(VI) Saeednia, Samira Sheikhshoaie, Iran Stoeckli-Evans, Helen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, [Mo(C(11)H(13)NO(3))O(2)(CH(3)OH)], the Mo(VI) ion is octahedrally coordinated by two oxide O atoms, the N atom and two deprotonated OH groups of the tridentate Schiff base ligand 2-meth­oxy-6-[(2-oxidoprop­yl)imino­meth­yl]phenolate and by a methanol O atom. In the crystal structure, two complexes are linked via O—H⋯O hydrogen bonds, yielding a centrosymmetric arrangement involving the methanol hydr­oxy group and one of the ligand O atoms coordinated to the Mo(VI) ion. International Union of Crystallography 2009-11-18 /pmc/articles/PMC2972118/ /pubmed/21578621 http://dx.doi.org/10.1107/S1600536809047485 Text en © Saeednia et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Saeednia, Samira
Sheikhshoaie, Iran
Stoeckli-Evans, Helen
Methanol{2-meth­oxy-6-[(2-oxidoprop­yl)imino­meth­yl]phenolato}dioxidomolyb­denum(VI)
title Methanol{2-meth­oxy-6-[(2-oxidoprop­yl)imino­meth­yl]phenolato}dioxidomolyb­denum(VI)
title_full Methanol{2-meth­oxy-6-[(2-oxidoprop­yl)imino­meth­yl]phenolato}dioxidomolyb­denum(VI)
title_fullStr Methanol{2-meth­oxy-6-[(2-oxidoprop­yl)imino­meth­yl]phenolato}dioxidomolyb­denum(VI)
title_full_unstemmed Methanol{2-meth­oxy-6-[(2-oxidoprop­yl)imino­meth­yl]phenolato}dioxidomolyb­denum(VI)
title_short Methanol{2-meth­oxy-6-[(2-oxidoprop­yl)imino­meth­yl]phenolato}dioxidomolyb­denum(VI)
title_sort methanol{2-meth­oxy-6-[(2-oxidoprop­yl)imino­meth­yl]phenolato}dioxidomolyb­denum(vi)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972118/
https://www.ncbi.nlm.nih.gov/pubmed/21578621
http://dx.doi.org/10.1107/S1600536809047485
work_keys_str_mv AT saeedniasamira methanol2methoxy62oxidopropyliminomethylphenolatodioxidomolybdenumvi
AT sheikhshoaieiran methanol2methoxy62oxidopropyliminomethylphenolatodioxidomolybdenumvi
AT stoecklievanshelen methanol2methoxy62oxidopropyliminomethylphenolatodioxidomolybdenumvi

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