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Diaquabis(N,N′-dibenzylethane-1,2-diamine-κ(2) N,N′)nickel(II) dichloride N,N-dimethylformamide solvate
The asymmetric unit of the title complex, [Ni(C(16)H(20)N(2))(2)(H(2)O)(2)]Cl(2)·C(3)H(7)NO, consists of two Ni(II) atoms, each lying on an inversion center, two Cl anions, two N,N′-dibenzylethane-1,2-diamine ligands, two coordinated water molecules and one N,N-dimethylformamide solvent molecule...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972121/ https://www.ncbi.nlm.nih.gov/pubmed/21578571 http://dx.doi.org/10.1107/S1600536809046042 |
Sumario: | The asymmetric unit of the title complex, [Ni(C(16)H(20)N(2))(2)(H(2)O)(2)]Cl(2)·C(3)H(7)NO, consists of two Ni(II) atoms, each lying on an inversion center, two Cl anions, two N,N′-dibenzylethane-1,2-diamine ligands, two coordinated water molecules and one N,N-dimethylformamide solvent molecule. Each Ni(II) atom is six-coordinated in a distorted octahedral coordination geometry, with the equatorial plane formed by four N atoms and the axial positions occupied by two water molecules. The complex molecules are linked into a chain along [001] by N—H⋯Cl, N—H⋯O and O—H⋯Cl hydrogen bonds. The C atoms and H atoms of the solvent molecule are disordered over two sites in a ratio of 0.52 (2):0.48 (2). |
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