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Diaqua­bis(N,N′-dibenzyl­ethane-1,2-diamine-κ(2) N,N′)nickel(II) dichloride N,N-dimethyl­formamide solvate

The asymmetric unit of the title complex, [Ni(C(16)H(20)N(2))(2)(H(2)O)(2)]Cl(2)·C(3)H(7)NO, consists of two Ni(II) atoms, each lying on an inversion center, two Cl anions, two N,N′-dibenzyl­ethane-1,2-diamine ligands, two coordinated water mol­ecules and one N,N-dimethyl­formamide solvent mol­ecule...

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Detalles Bibliográficos
Autores principales: Liu, Yu-Fen, Xia, Hai-Tao, Wang, Da-Qi, Gong, Xiao-Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972121/
https://www.ncbi.nlm.nih.gov/pubmed/21578571
http://dx.doi.org/10.1107/S1600536809046042
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author Liu, Yu-Fen
Xia, Hai-Tao
Wang, Da-Qi
Gong, Xiao-Lin
author_facet Liu, Yu-Fen
Xia, Hai-Tao
Wang, Da-Qi
Gong, Xiao-Lin
author_sort Liu, Yu-Fen
collection PubMed
description The asymmetric unit of the title complex, [Ni(C(16)H(20)N(2))(2)(H(2)O)(2)]Cl(2)·C(3)H(7)NO, consists of two Ni(II) atoms, each lying on an inversion center, two Cl anions, two N,N′-dibenzyl­ethane-1,2-diamine ligands, two coordinated water mol­ecules and one N,N-dimethyl­formamide solvent mol­ecule. Each Ni(II) atom is six-coordinated in a distorted octa­hedral coordination geometry, with the equatorial plane formed by four N atoms and the axial positions occupied by two water mol­ecules. The complex mol­ecules are linked into a chain along [001] by N—H⋯Cl, N—H⋯O and O—H⋯Cl hydrogen bonds. The C atoms and H atoms of the solvent mol­ecule are disordered over two sites in a ratio of 0.52 (2):0.48 (2).
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spelling pubmed-29721212010-12-30 Diaqua­bis(N,N′-dibenzyl­ethane-1,2-diamine-κ(2) N,N′)nickel(II) dichloride N,N-dimethyl­formamide solvate Liu, Yu-Fen Xia, Hai-Tao Wang, Da-Qi Gong, Xiao-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Ni(C(16)H(20)N(2))(2)(H(2)O)(2)]Cl(2)·C(3)H(7)NO, consists of two Ni(II) atoms, each lying on an inversion center, two Cl anions, two N,N′-dibenzyl­ethane-1,2-diamine ligands, two coordinated water mol­ecules and one N,N-dimethyl­formamide solvent mol­ecule. Each Ni(II) atom is six-coordinated in a distorted octa­hedral coordination geometry, with the equatorial plane formed by four N atoms and the axial positions occupied by two water mol­ecules. The complex mol­ecules are linked into a chain along [001] by N—H⋯Cl, N—H⋯O and O—H⋯Cl hydrogen bonds. The C atoms and H atoms of the solvent mol­ecule are disordered over two sites in a ratio of 0.52 (2):0.48 (2). International Union of Crystallography 2009-11-07 /pmc/articles/PMC2972121/ /pubmed/21578571 http://dx.doi.org/10.1107/S1600536809046042 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Yu-Fen
Xia, Hai-Tao
Wang, Da-Qi
Gong, Xiao-Lin
Diaqua­bis(N,N′-dibenzyl­ethane-1,2-diamine-κ(2) N,N′)nickel(II) dichloride N,N-dimethyl­formamide solvate
title Diaqua­bis(N,N′-dibenzyl­ethane-1,2-diamine-κ(2) N,N′)nickel(II) dichloride N,N-dimethyl­formamide solvate
title_full Diaqua­bis(N,N′-dibenzyl­ethane-1,2-diamine-κ(2) N,N′)nickel(II) dichloride N,N-dimethyl­formamide solvate
title_fullStr Diaqua­bis(N,N′-dibenzyl­ethane-1,2-diamine-κ(2) N,N′)nickel(II) dichloride N,N-dimethyl­formamide solvate
title_full_unstemmed Diaqua­bis(N,N′-dibenzyl­ethane-1,2-diamine-κ(2) N,N′)nickel(II) dichloride N,N-dimethyl­formamide solvate
title_short Diaqua­bis(N,N′-dibenzyl­ethane-1,2-diamine-κ(2) N,N′)nickel(II) dichloride N,N-dimethyl­formamide solvate
title_sort diaqua­bis(n,n′-dibenzyl­ethane-1,2-diamine-κ(2) n,n′)nickel(ii) dichloride n,n-dimethyl­formamide solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972121/
https://www.ncbi.nlm.nih.gov/pubmed/21578571
http://dx.doi.org/10.1107/S1600536809046042
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