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Diaquabis(N,N′-dibenzylethane-1,2-diamine-κ(2) N,N′)nickel(II) dichloride N,N-dimethylformamide solvate
The asymmetric unit of the title complex, [Ni(C(16)H(20)N(2))(2)(H(2)O)(2)]Cl(2)·C(3)H(7)NO, consists of two Ni(II) atoms, each lying on an inversion center, two Cl anions, two N,N′-dibenzylethane-1,2-diamine ligands, two coordinated water molecules and one N,N-dimethylformamide solvent molecule...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972121/ https://www.ncbi.nlm.nih.gov/pubmed/21578571 http://dx.doi.org/10.1107/S1600536809046042 |
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author | Liu, Yu-Fen Xia, Hai-Tao Wang, Da-Qi Gong, Xiao-Lin |
author_facet | Liu, Yu-Fen Xia, Hai-Tao Wang, Da-Qi Gong, Xiao-Lin |
author_sort | Liu, Yu-Fen |
collection | PubMed |
description | The asymmetric unit of the title complex, [Ni(C(16)H(20)N(2))(2)(H(2)O)(2)]Cl(2)·C(3)H(7)NO, consists of two Ni(II) atoms, each lying on an inversion center, two Cl anions, two N,N′-dibenzylethane-1,2-diamine ligands, two coordinated water molecules and one N,N-dimethylformamide solvent molecule. Each Ni(II) atom is six-coordinated in a distorted octahedral coordination geometry, with the equatorial plane formed by four N atoms and the axial positions occupied by two water molecules. The complex molecules are linked into a chain along [001] by N—H⋯Cl, N—H⋯O and O—H⋯Cl hydrogen bonds. The C atoms and H atoms of the solvent molecule are disordered over two sites in a ratio of 0.52 (2):0.48 (2). |
format | Text |
id | pubmed-2972121 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29721212010-12-30 Diaquabis(N,N′-dibenzylethane-1,2-diamine-κ(2) N,N′)nickel(II) dichloride N,N-dimethylformamide solvate Liu, Yu-Fen Xia, Hai-Tao Wang, Da-Qi Gong, Xiao-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Ni(C(16)H(20)N(2))(2)(H(2)O)(2)]Cl(2)·C(3)H(7)NO, consists of two Ni(II) atoms, each lying on an inversion center, two Cl anions, two N,N′-dibenzylethane-1,2-diamine ligands, two coordinated water molecules and one N,N-dimethylformamide solvent molecule. Each Ni(II) atom is six-coordinated in a distorted octahedral coordination geometry, with the equatorial plane formed by four N atoms and the axial positions occupied by two water molecules. The complex molecules are linked into a chain along [001] by N—H⋯Cl, N—H⋯O and O—H⋯Cl hydrogen bonds. The C atoms and H atoms of the solvent molecule are disordered over two sites in a ratio of 0.52 (2):0.48 (2). International Union of Crystallography 2009-11-07 /pmc/articles/PMC2972121/ /pubmed/21578571 http://dx.doi.org/10.1107/S1600536809046042 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Yu-Fen Xia, Hai-Tao Wang, Da-Qi Gong, Xiao-Lin Diaquabis(N,N′-dibenzylethane-1,2-diamine-κ(2) N,N′)nickel(II) dichloride N,N-dimethylformamide solvate |
title | Diaquabis(N,N′-dibenzylethane-1,2-diamine-κ(2)
N,N′)nickel(II) dichloride N,N-dimethylformamide solvate |
title_full | Diaquabis(N,N′-dibenzylethane-1,2-diamine-κ(2)
N,N′)nickel(II) dichloride N,N-dimethylformamide solvate |
title_fullStr | Diaquabis(N,N′-dibenzylethane-1,2-diamine-κ(2)
N,N′)nickel(II) dichloride N,N-dimethylformamide solvate |
title_full_unstemmed | Diaquabis(N,N′-dibenzylethane-1,2-diamine-κ(2)
N,N′)nickel(II) dichloride N,N-dimethylformamide solvate |
title_short | Diaquabis(N,N′-dibenzylethane-1,2-diamine-κ(2)
N,N′)nickel(II) dichloride N,N-dimethylformamide solvate |
title_sort | diaquabis(n,n′-dibenzylethane-1,2-diamine-κ(2)
n,n′)nickel(ii) dichloride n,n-dimethylformamide solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972121/ https://www.ncbi.nlm.nih.gov/pubmed/21578571 http://dx.doi.org/10.1107/S1600536809046042 |
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