[N,N′-Bis(3-meth­oxy-2-oxidobenzyl­idene)ethyl­enediammonium-κ(4) O,O′,O′′,O′′′]tris­(nitrato-κ(2) O,O′)dysprosium(III)

In the title mononuclear Schiff base complex, [Dy(NO(3))(3)(C(18)H(20)N(2)O(4))], the Dy(III) ion is ten-coordinated in a distorted hexa­deca­hedral geometry by six O atoms of three nitrate anions and four O atoms of the Schiff base ligand. An intra­molecular N—H⋯O hydrogen bond occurs. The crystal...

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Detalles Bibliográficos
Autores principales: Gao, Ting, Li, Guang-Ming, Gao, Po, Yan, Peng-Fei, Hou, Guang-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972125/
https://www.ncbi.nlm.nih.gov/pubmed/21578615
http://dx.doi.org/10.1107/S1600536809047436
Descripción
Sumario:In the title mononuclear Schiff base complex, [Dy(NO(3))(3)(C(18)H(20)N(2)O(4))], the Dy(III) ion is ten-coordinated in a distorted hexa­deca­hedral geometry by six O atoms of three nitrate anions and four O atoms of the Schiff base ligand. An intra­molecular N—H⋯O hydrogen bond occurs. The crystal structure is stabilized by inter­molecular C—H⋯O hydrogen bonds.

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