Aqua­{4,4′-dibromo-6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II)

The title complex, [Cu(C(18)H(16)Br(2)N(2)O(4))(H(2)O)], lies on a crystallographic mirror plane with the Cu(II) ion coordinated by two N atoms and two O atoms of a tetra­dentate Schiff base ligand and one O atom from a water ligand in a slightly distorted square-pyramidal environment. The mirror pl...

Descripción completa

Detalles Bibliográficos
Autor principal: Xie, Hai
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972126/
https://www.ncbi.nlm.nih.gov/pubmed/21578609
http://dx.doi.org/10.1107/S1600536809046212
_version_ 1782190750531846144
author Xie, Hai
author_facet Xie, Hai
author_sort Xie, Hai
collection PubMed
description The title complex, [Cu(C(18)H(16)Br(2)N(2)O(4))(H(2)O)], lies on a crystallographic mirror plane with the Cu(II) ion coordinated by two N atoms and two O atoms of a tetra­dentate Schiff base ligand and one O atom from a water ligand in a slightly distorted square-pyramidal environment. The mirror plane, which coincides with the Cu—O(water) bond, imposes disorder of the atoms of the ethyl­ene group. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link complex mol­ecules into extended chains along [100].
format Text
id pubmed-2972126
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29721262010-12-30 Aqua­{4,4′-dibromo-6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II) Xie, Hai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(C(18)H(16)Br(2)N(2)O(4))(H(2)O)], lies on a crystallographic mirror plane with the Cu(II) ion coordinated by two N atoms and two O atoms of a tetra­dentate Schiff base ligand and one O atom from a water ligand in a slightly distorted square-pyramidal environment. The mirror plane, which coincides with the Cu—O(water) bond, imposes disorder of the atoms of the ethyl­ene group. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link complex mol­ecules into extended chains along [100]. International Union of Crystallography 2009-11-14 /pmc/articles/PMC2972126/ /pubmed/21578609 http://dx.doi.org/10.1107/S1600536809046212 Text en © Hai Xie 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xie, Hai
Aqua­{4,4′-dibromo-6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II)
title Aqua­{4,4′-dibromo-6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II)
title_full Aqua­{4,4′-dibromo-6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II)
title_fullStr Aqua­{4,4′-dibromo-6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II)
title_full_unstemmed Aqua­{4,4′-dibromo-6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II)
title_short Aqua­{4,4′-dibromo-6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(II)
title_sort aqua­{4,4′-dibromo-6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972126/
https://www.ncbi.nlm.nih.gov/pubmed/21578609
http://dx.doi.org/10.1107/S1600536809046212
work_keys_str_mv AT xiehai aqua44dibromo66dimethoxy22ethane12diylbisnitrilomethylidynediphenolatocopperii

Ejemplares similares