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cis-1,2-Bis{[4-(4-pyridyl)pyrimidin-2-yl]sulfanylmethyl}benzene
The molecular skeleton of the title molecule, C(26)H(20)N(6)S(2), adopts a cis conformation with the two arms positioned on one side of the benzene ring plane. Intramolecular π–π interactions between the pyrimidine rings [centroid–centroid distance = 3.654 (2) Å] and between the pyridine rings [...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972128/ https://www.ncbi.nlm.nih.gov/pubmed/21578717 http://dx.doi.org/10.1107/S1600536809045450 |
Sumario: | The molecular skeleton of the title molecule, C(26)H(20)N(6)S(2), adopts a cis conformation with the two arms positioned on one side of the benzene ring plane. Intramolecular π–π interactions between the pyrimidine rings [centroid–centroid distance = 3.654 (2) Å] and between the pyridine rings [centroid–centroid distance = 3.775 (2) Å] help to set the molecular conformation; the pyrimidine rings, as well as the pyridine rings, are nearly parallel, forming dihedral angles of 4.12 (14) and 2.46 (14)°, respectively. |
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