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cis-1,2-Bis{[4-(4-pyrid­yl)pyrimidin-2-yl]sulfanylmeth­yl}benzene

The mol­ecular skeleton of the title mol­ecule, C(26)H(20)N(6)S(2), adopts a cis conformation with the two arms positioned on one side of the benzene ring plane. Intra­molecular π–π inter­actions between the pyrimidine rings [centroid–centroid distance = 3.654 (2) Å] and between the pyridine rings [...

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Detalles Bibliográficos
Autores principales: Dong, Hua-Ze, Zhu, Hai-Bin, Gou, Shao-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972128/
https://www.ncbi.nlm.nih.gov/pubmed/21578717
http://dx.doi.org/10.1107/S1600536809045450
Descripción
Sumario:The mol­ecular skeleton of the title mol­ecule, C(26)H(20)N(6)S(2), adopts a cis conformation with the two arms positioned on one side of the benzene ring plane. Intra­molecular π–π inter­actions between the pyrimidine rings [centroid–centroid distance = 3.654 (2) Å] and between the pyridine rings [centroid–centroid distance = 3.775 (2) Å] help to set the mol­ecular conformation; the pyrimidine rings, as well as the pyridine rings, are nearly parallel, forming dihedral angles of 4.12 (14) and 2.46 (14)°, respectively.