cis-1,2-Bis{[4-(4-pyrid­yl)pyrimidin-2-yl]sulfanylmeth­yl}benzene

The mol­ecular skeleton of the title mol­ecule, C(26)H(20)N(6)S(2), adopts a cis conformation with the two arms positioned on one side of the benzene ring plane. Intra­molecular π–π inter­actions between the pyrimidine rings [centroid–centroid distance = 3.654 (2) Å] and between the pyridine rings [...

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Detalles Bibliográficos
Autores principales: Dong, Hua-Ze, Zhu, Hai-Bin, Gou, Shao-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972128/
https://www.ncbi.nlm.nih.gov/pubmed/21578717
http://dx.doi.org/10.1107/S1600536809045450
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author Dong, Hua-Ze
Zhu, Hai-Bin
Gou, Shao-Hua
author_facet Dong, Hua-Ze
Zhu, Hai-Bin
Gou, Shao-Hua
author_sort Dong, Hua-Ze
collection PubMed
description The mol­ecular skeleton of the title mol­ecule, C(26)H(20)N(6)S(2), adopts a cis conformation with the two arms positioned on one side of the benzene ring plane. Intra­molecular π–π inter­actions between the pyrimidine rings [centroid–centroid distance = 3.654 (2) Å] and between the pyridine rings [centroid–centroid distance = 3.775 (2) Å] help to set the mol­ecular conformation; the pyrimidine rings, as well as the pyridine rings, are nearly parallel, forming dihedral angles of 4.12 (14) and 2.46 (14)°, respectively.
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spelling pubmed-29721282010-12-30 cis-1,2-Bis{[4-(4-pyrid­yl)pyrimidin-2-yl]sulfanylmeth­yl}benzene Dong, Hua-Ze Zhu, Hai-Bin Gou, Shao-Hua Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecular skeleton of the title mol­ecule, C(26)H(20)N(6)S(2), adopts a cis conformation with the two arms positioned on one side of the benzene ring plane. Intra­molecular π–π inter­actions between the pyrimidine rings [centroid–centroid distance = 3.654 (2) Å] and between the pyridine rings [centroid–centroid distance = 3.775 (2) Å] help to set the mol­ecular conformation; the pyrimidine rings, as well as the pyridine rings, are nearly parallel, forming dihedral angles of 4.12 (14) and 2.46 (14)°, respectively. International Union of Crystallography 2009-11-04 /pmc/articles/PMC2972128/ /pubmed/21578717 http://dx.doi.org/10.1107/S1600536809045450 Text en © Dong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dong, Hua-Ze
Zhu, Hai-Bin
Gou, Shao-Hua
cis-1,2-Bis{[4-(4-pyrid­yl)pyrimidin-2-yl]sulfanylmeth­yl}benzene
title cis-1,2-Bis{[4-(4-pyrid­yl)pyrimidin-2-yl]sulfanylmeth­yl}benzene
title_full cis-1,2-Bis{[4-(4-pyrid­yl)pyrimidin-2-yl]sulfanylmeth­yl}benzene
title_fullStr cis-1,2-Bis{[4-(4-pyrid­yl)pyrimidin-2-yl]sulfanylmeth­yl}benzene
title_full_unstemmed cis-1,2-Bis{[4-(4-pyrid­yl)pyrimidin-2-yl]sulfanylmeth­yl}benzene
title_short cis-1,2-Bis{[4-(4-pyrid­yl)pyrimidin-2-yl]sulfanylmeth­yl}benzene
title_sort cis-1,2-bis{[4-(4-pyrid­yl)pyrimidin-2-yl]sulfanylmeth­yl}benzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972128/
https://www.ncbi.nlm.nih.gov/pubmed/21578717
http://dx.doi.org/10.1107/S1600536809045450
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AT zhuhaibin cis12bis44pyridylpyrimidin2ylsulfanylmethylbenzene
AT goushaohua cis12bis44pyridylpyrimidin2ylsulfanylmethylbenzene

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