Dimethyl 11,13-dimethyl-16-[1,2-bis­(methoxy­carbon­yl)ethen­yl]-12-oxo-16,17-dioxa-18-aza­hexa­cyclo­[7.5.1.1(1,4).1(6,9).1(10,14).0(5,15)]octa­deca-2,7-diene-2,3-dicarboxyl­ate

The title compound, C(27)H(29)NO(11), is a product of the tandem ‘domino’ Diels–Alder reaction. The mol­ecule comprises a fused hexa­cyclic system containing four five-membered rings (two dihydro­furan and two tetra­hydro­furan) in the usual envelope conformations and two six-membered rings (tetra­h...

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Autores principales: Gurbanov, Atash V., Nikitina, Eugeniya V., Sorokina, Elena A., Zubkov, Fedor I., Khrustalev, Victor N.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972130/
https://www.ncbi.nlm.nih.gov/pubmed/21578945
http://dx.doi.org/10.1107/S1600536809050600
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author Gurbanov, Atash V.
Nikitina, Eugeniya V.
Sorokina, Elena A.
Zubkov, Fedor I.
Khrustalev, Victor N.
author_facet Gurbanov, Atash V.
Nikitina, Eugeniya V.
Sorokina, Elena A.
Zubkov, Fedor I.
Khrustalev, Victor N.
author_sort Gurbanov, Atash V.
collection PubMed
description The title compound, C(27)H(29)NO(11), is a product of the tandem ‘domino’ Diels–Alder reaction. The mol­ecule comprises a fused hexa­cyclic system containing four five-membered rings (two dihydro­furan and two tetra­hydro­furan) in the usual envelope conformations and two six-membered rings (tetra­hydro­pyridinone and piperidine) adopting slightly flattened boat and chair conformations, respectively. The dispositions of the carboxyl­ate substituents relative to each other are determined by both steric reasons and inter­molecular C—H⋯O hydrogen bonding and attractive anti­parallel C=O⋯C=O inter­actions [C⋯O = 2.995 (2) Å].
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spelling pubmed-29721302010-12-30 Dimethyl 11,13-dimethyl-16-[1,2-bis­(methoxy­carbon­yl)ethen­yl]-12-oxo-16,17-dioxa-18-aza­hexa­cyclo­[7.5.1.1(1,4).1(6,9).1(10,14).0(5,15)]octa­deca-2,7-diene-2,3-dicarboxyl­ate Gurbanov, Atash V. Nikitina, Eugeniya V. Sorokina, Elena A. Zubkov, Fedor I. Khrustalev, Victor N. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(27)H(29)NO(11), is a product of the tandem ‘domino’ Diels–Alder reaction. The mol­ecule comprises a fused hexa­cyclic system containing four five-membered rings (two dihydro­furan and two tetra­hydro­furan) in the usual envelope conformations and two six-membered rings (tetra­hydro­pyridinone and piperidine) adopting slightly flattened boat and chair conformations, respectively. The dispositions of the carboxyl­ate substituents relative to each other are determined by both steric reasons and inter­molecular C—H⋯O hydrogen bonding and attractive anti­parallel C=O⋯C=O inter­actions [C⋯O = 2.995 (2) Å]. International Union of Crystallography 2009-11-28 /pmc/articles/PMC2972130/ /pubmed/21578945 http://dx.doi.org/10.1107/S1600536809050600 Text en © Gurbanov et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gurbanov, Atash V.
Nikitina, Eugeniya V.
Sorokina, Elena A.
Zubkov, Fedor I.
Khrustalev, Victor N.
Dimethyl 11,13-dimethyl-16-[1,2-bis­(methoxy­carbon­yl)ethen­yl]-12-oxo-16,17-dioxa-18-aza­hexa­cyclo­[7.5.1.1(1,4).1(6,9).1(10,14).0(5,15)]octa­deca-2,7-diene-2,3-dicarboxyl­ate
title Dimethyl 11,13-dimethyl-16-[1,2-bis­(methoxy­carbon­yl)ethen­yl]-12-oxo-16,17-dioxa-18-aza­hexa­cyclo­[7.5.1.1(1,4).1(6,9).1(10,14).0(5,15)]octa­deca-2,7-diene-2,3-dicarboxyl­ate
title_full Dimethyl 11,13-dimethyl-16-[1,2-bis­(methoxy­carbon­yl)ethen­yl]-12-oxo-16,17-dioxa-18-aza­hexa­cyclo­[7.5.1.1(1,4).1(6,9).1(10,14).0(5,15)]octa­deca-2,7-diene-2,3-dicarboxyl­ate
title_fullStr Dimethyl 11,13-dimethyl-16-[1,2-bis­(methoxy­carbon­yl)ethen­yl]-12-oxo-16,17-dioxa-18-aza­hexa­cyclo­[7.5.1.1(1,4).1(6,9).1(10,14).0(5,15)]octa­deca-2,7-diene-2,3-dicarboxyl­ate
title_full_unstemmed Dimethyl 11,13-dimethyl-16-[1,2-bis­(methoxy­carbon­yl)ethen­yl]-12-oxo-16,17-dioxa-18-aza­hexa­cyclo­[7.5.1.1(1,4).1(6,9).1(10,14).0(5,15)]octa­deca-2,7-diene-2,3-dicarboxyl­ate
title_short Dimethyl 11,13-dimethyl-16-[1,2-bis­(methoxy­carbon­yl)ethen­yl]-12-oxo-16,17-dioxa-18-aza­hexa­cyclo­[7.5.1.1(1,4).1(6,9).1(10,14).0(5,15)]octa­deca-2,7-diene-2,3-dicarboxyl­ate
title_sort dimethyl 11,13-dimethyl-16-[1,2-bis­(methoxy­carbon­yl)ethen­yl]-12-oxo-16,17-dioxa-18-aza­hexa­cyclo­[7.5.1.1(1,4).1(6,9).1(10,14).0(5,15)]octa­deca-2,7-diene-2,3-dicarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972130/
https://www.ncbi.nlm.nih.gov/pubmed/21578945
http://dx.doi.org/10.1107/S1600536809050600
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AT khrustalevvictorn dimethyl1113dimethyl1612bismethoxycarbonylethenyl12oxo1617dioxa18azahexacyclo751114169110140515octadeca27diene23dicarboxylate

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