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μ-Bis(diphenylarsino)methane-1:2κ(2) As:As-nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(2-methoxyphenyl)diphenylphosphino-3κP]-triangulo-triruthenium(0)
In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(19)H(17)OP)(CO)(9)], the bis(diphenylarsino)methane ligand bridges a Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru(3) tr...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972135/ https://www.ncbi.nlm.nih.gov/pubmed/21578647 http://dx.doi.org/10.1107/S1600536809047783 |
| _version_ | 1782190752690864128 |
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| author | Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun |
| author_facet | Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun |
| author_sort | Shawkataly, Omar bin |
| collection | PubMed |
| description | In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(19)H(17)OP)(CO)(9)], the bis(diphenylarsino)methane ligand bridges a Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru(3) triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phosphine substituted phenyl rings make dihedral angles of 74.34 (12), 68.34 (12) and 85.45 (11)° with each other. The dihedral angles between the two phenyl rings are 87.56 (11) and 60.56 (11)° for the two diphenylarsino groups. In the crystal packing, the molecules are linked together into chains via intermolecular C—H⋯O hydrogen bonds down the a axis. Weak intermolecular C—H⋯π interactions further stabilize the crystal structure. |
| format | Text |
| id | pubmed-2972135 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29721352010-12-30 μ-Bis(diphenylarsino)methane-1:2κ(2) As:As-nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(2-methoxyphenyl)diphenylphosphino-3κP]-triangulo-triruthenium(0) Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(19)H(17)OP)(CO)(9)], the bis(diphenylarsino)methane ligand bridges a Ru—Ru bond and the monodentate phosphine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru(3) triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phosphine substituted phenyl rings make dihedral angles of 74.34 (12), 68.34 (12) and 85.45 (11)° with each other. The dihedral angles between the two phenyl rings are 87.56 (11) and 60.56 (11)° for the two diphenylarsino groups. In the crystal packing, the molecules are linked together into chains via intermolecular C—H⋯O hydrogen bonds down the a axis. Weak intermolecular C—H⋯π interactions further stabilize the crystal structure. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2972135/ /pubmed/21578647 http://dx.doi.org/10.1107/S1600536809047783 Text en © Shawkataly et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shawkataly, Omar bin Khan, Imthyaz Ahmed Yeap, Chin Sing Fun, Hoong-Kun μ-Bis(diphenylarsino)methane-1:2κ(2) As:As-nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(2-methoxyphenyl)diphenylphosphino-3κP]-triangulo-triruthenium(0) |
| title | μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As-nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[(2-methoxyphenyl)diphenylphosphino-3κP]-triangulo-triruthenium(0) |
| title_full | μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As-nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[(2-methoxyphenyl)diphenylphosphino-3κP]-triangulo-triruthenium(0) |
| title_fullStr | μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As-nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[(2-methoxyphenyl)diphenylphosphino-3κP]-triangulo-triruthenium(0) |
| title_full_unstemmed | μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As-nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[(2-methoxyphenyl)diphenylphosphino-3κP]-triangulo-triruthenium(0) |
| title_short | μ-Bis(diphenylarsino)methane-1:2κ(2)
As:As-nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[(2-methoxyphenyl)diphenylphosphino-3κP]-triangulo-triruthenium(0) |
| title_sort | μ-bis(diphenylarsino)methane-1:2κ(2)
as:as-nonacarbonyl-1κ(3)
c,2κ(3)
c,3κ(3)
c-[(2-methoxyphenyl)diphenylphosphino-3κp]-triangulo-triruthenium(0) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972135/ https://www.ncbi.nlm.nih.gov/pubmed/21578647 http://dx.doi.org/10.1107/S1600536809047783 |
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