2,3-O-Isopropyl­idene-3-C-phenyl­erythrofuran­ose

The title compound, C(13)H(16)O, comprises two fused five-membered rings. Each ring has an envelope conformation, with the ether O atom in the furan­ose ring, and the CMe(2) atom in the acetonide ring as the flap atoms. In the crystal, centrosymmetrically related mol­ecules associate via hydr­oxy–et...

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Detalles Bibliográficos
Autores principales: Robinson, Tony V., Taylor, Dennis K., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972136/
https://www.ncbi.nlm.nih.gov/pubmed/21578852
http://dx.doi.org/10.1107/S160053680904848X
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author Robinson, Tony V.
Taylor, Dennis K.
Tiekink, Edward R. T.
author_facet Robinson, Tony V.
Taylor, Dennis K.
Tiekink, Edward R. T.
author_sort Robinson, Tony V.
collection PubMed
description The title compound, C(13)H(16)O, comprises two fused five-membered rings. Each ring has an envelope conformation, with the ether O atom in the furan­ose ring, and the CMe(2) atom in the acetonide ring as the flap atoms. In the crystal, centrosymmetrically related mol­ecules associate via hydr­oxy–ether O—H⋯O hydrogen bonds and the resulting dimers are linked into a supra­molecular chain with a flattened topology via C—H⋯O(hydr­oxy) contacts, and aligned in the a-axis direction.
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spelling pubmed-29721362010-12-30 2,3-O-Isopropyl­idene-3-C-phenyl­erythrofuran­ose Robinson, Tony V. Taylor, Dennis K. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(16)O, comprises two fused five-membered rings. Each ring has an envelope conformation, with the ether O atom in the furan­ose ring, and the CMe(2) atom in the acetonide ring as the flap atoms. In the crystal, centrosymmetrically related mol­ecules associate via hydr­oxy–ether O—H⋯O hydrogen bonds and the resulting dimers are linked into a supra­molecular chain with a flattened topology via C—H⋯O(hydr­oxy) contacts, and aligned in the a-axis direction. International Union of Crystallography 2009-11-21 /pmc/articles/PMC2972136/ /pubmed/21578852 http://dx.doi.org/10.1107/S160053680904848X Text en © Robinson et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Robinson, Tony V.
Taylor, Dennis K.
Tiekink, Edward R. T.
2,3-O-Isopropyl­idene-3-C-phenyl­erythrofuran­ose
title 2,3-O-Isopropyl­idene-3-C-phenyl­erythrofuran­ose
title_full 2,3-O-Isopropyl­idene-3-C-phenyl­erythrofuran­ose
title_fullStr 2,3-O-Isopropyl­idene-3-C-phenyl­erythrofuran­ose
title_full_unstemmed 2,3-O-Isopropyl­idene-3-C-phenyl­erythrofuran­ose
title_short 2,3-O-Isopropyl­idene-3-C-phenyl­erythrofuran­ose
title_sort 2,3-o-isopropyl­idene-3-c-phenyl­erythrofuran­ose
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972136/
https://www.ncbi.nlm.nih.gov/pubmed/21578852
http://dx.doi.org/10.1107/S160053680904848X
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AT taylordennisk 23oisopropylidene3cphenylerythrofuranose
AT tiekinkedwardrt 23oisopropylidene3cphenylerythrofuranose

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