Carbon­yl(N-nitroso-N-oxido-1-naphtylamine-κ(2) O,O′)(triphenyl­phosphine-κP)rhodium(I) acetone solvate

The title compound, [Rh(C(10)H(7)N(2)O(2))(C(18)H(15)P)(CO)]·(CH(3))(2)CO, is the second structural report of a metal complex formed with the O,O′-C(10)H(7)N(2)O(2) (neocupferrate) ligand. In the crystal structure, the metal centre is surrounded by one carbonyl ligand, one triphenyl­phosphine ligand...

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Detalles Bibliográficos
Autores principales: Venter, Johan A., Purcell, W., Visser, H. G., Muller, T. J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972147/
https://www.ncbi.nlm.nih.gov/pubmed/21578610
http://dx.doi.org/10.1107/S1600536809047321
Descripción
Sumario:The title compound, [Rh(C(10)H(7)N(2)O(2))(C(18)H(15)P)(CO)]·(CH(3))(2)CO, is the second structural report of a metal complex formed with the O,O′-C(10)H(7)N(2)O(2) (neocupferrate) ligand. In the crystal structure, the metal centre is surrounded by one carbonyl ligand, one triphenyl­phosphine ligand and the bidentate neocupferrate ligand, forming a distorted square-planar RhCO(2)P coordination set which is best illustrated by the small O—Rh—O bite angle of 77.74 (10)°. There are no classical hydrogen-bond inter­actions observed for this complex.

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