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Carbonyl(N-nitroso-N-oxido-1-naphtylamine-κ(2) O,O′)(triphenylphosphine-κP)rhodium(I) acetone solvate
The title compound, [Rh(C(10)H(7)N(2)O(2))(C(18)H(15)P)(CO)]·(CH(3))(2)CO, is the second structural report of a metal complex formed with the O,O′-C(10)H(7)N(2)O(2) (neocupferrate) ligand. In the crystal structure, the metal centre is surrounded by one carbonyl ligand, one triphenylphosphine ligand...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972147/ https://www.ncbi.nlm.nih.gov/pubmed/21578610 http://dx.doi.org/10.1107/S1600536809047321 |
| _version_ | 1782190755728588800 |
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| author | Venter, Johan A. Purcell, W. Visser, H. G. Muller, T. J. |
| author_facet | Venter, Johan A. Purcell, W. Visser, H. G. Muller, T. J. |
| author_sort | Venter, Johan A. |
| collection | PubMed |
| description | The title compound, [Rh(C(10)H(7)N(2)O(2))(C(18)H(15)P)(CO)]·(CH(3))(2)CO, is the second structural report of a metal complex formed with the O,O′-C(10)H(7)N(2)O(2) (neocupferrate) ligand. In the crystal structure, the metal centre is surrounded by one carbonyl ligand, one triphenylphosphine ligand and the bidentate neocupferrate ligand, forming a distorted square-planar RhCO(2)P coordination set which is best illustrated by the small O—Rh—O bite angle of 77.74 (10)°. There are no classical hydrogen-bond interactions observed for this complex. |
| format | Text |
| id | pubmed-2972147 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29721472010-12-30 Carbonyl(N-nitroso-N-oxido-1-naphtylamine-κ(2) O,O′)(triphenylphosphine-κP)rhodium(I) acetone solvate Venter, Johan A. Purcell, W. Visser, H. G. Muller, T. J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Rh(C(10)H(7)N(2)O(2))(C(18)H(15)P)(CO)]·(CH(3))(2)CO, is the second structural report of a metal complex formed with the O,O′-C(10)H(7)N(2)O(2) (neocupferrate) ligand. In the crystal structure, the metal centre is surrounded by one carbonyl ligand, one triphenylphosphine ligand and the bidentate neocupferrate ligand, forming a distorted square-planar RhCO(2)P coordination set which is best illustrated by the small O—Rh—O bite angle of 77.74 (10)°. There are no classical hydrogen-bond interactions observed for this complex. International Union of Crystallography 2009-11-14 /pmc/articles/PMC2972147/ /pubmed/21578610 http://dx.doi.org/10.1107/S1600536809047321 Text en © Venter et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Venter, Johan A. Purcell, W. Visser, H. G. Muller, T. J. Carbonyl(N-nitroso-N-oxido-1-naphtylamine-κ(2) O,O′)(triphenylphosphine-κP)rhodium(I) acetone solvate |
| title | Carbonyl(N-nitroso-N-oxido-1-naphtylamine-κ(2)
O,O′)(triphenylphosphine-κP)rhodium(I) acetone solvate |
| title_full | Carbonyl(N-nitroso-N-oxido-1-naphtylamine-κ(2)
O,O′)(triphenylphosphine-κP)rhodium(I) acetone solvate |
| title_fullStr | Carbonyl(N-nitroso-N-oxido-1-naphtylamine-κ(2)
O,O′)(triphenylphosphine-κP)rhodium(I) acetone solvate |
| title_full_unstemmed | Carbonyl(N-nitroso-N-oxido-1-naphtylamine-κ(2)
O,O′)(triphenylphosphine-κP)rhodium(I) acetone solvate |
| title_short | Carbonyl(N-nitroso-N-oxido-1-naphtylamine-κ(2)
O,O′)(triphenylphosphine-κP)rhodium(I) acetone solvate |
| title_sort | carbonyl(n-nitroso-n-oxido-1-naphtylamine-κ(2)
o,o′)(triphenylphosphine-κp)rhodium(i) acetone solvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972147/ https://www.ncbi.nlm.nih.gov/pubmed/21578610 http://dx.doi.org/10.1107/S1600536809047321 |
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