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Bis[N,N′-bis(2,6-diisopropylphenyl)ethane-1,2-diimine]-1κ(2) N,N′;2κ(2) N,N′-tri-μ-trichlorido-1:2κ(6) Cl:Cl-chlorido-1κCl-tetrahydrofuran-2κO-dichromium(II) dichloromethane 4.5-solvate
In the molecular structure of the title compound, [Cr(2)Cl(4)(C(26)H(36)N(2))(2)(C(4)H(8)O)]·4.5CH(2)Cl(2), the two Cr(II) centers are bridged by three Cl atoms, forming a dinuclear complex. Each Cr(II) center is coordinated by one chelating bis(2,6-diisopropylphenyl)ethane-1,2-diimine ligand vi...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972152/ https://www.ncbi.nlm.nih.gov/pubmed/21578607 http://dx.doi.org/10.1107/S1600536809047266 |
Sumario: | In the molecular structure of the title compound, [Cr(2)Cl(4)(C(26)H(36)N(2))(2)(C(4)H(8)O)]·4.5CH(2)Cl(2), the two Cr(II) centers are bridged by three Cl atoms, forming a dinuclear complex. Each Cr(II) center is coordinated by one chelating bis(2,6-diisopropylphenyl)ethane-1,2-diimine ligand via both N atoms. An additional chloride ion binds to one chromium center, whereas an additional tetrahydrofuran molecule coordinates to the second Cr(II) center. The coordination geometry at each Cr(II) center can be best described as distorted octahedral. |
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