Bis[N,N′-bis­(2,6-diisopropyl­phen­yl)ethane-1,2-diimine]-1κ(2) N,N′;2κ(2) N,N′-tri-μ-trichlorido-1:2κ(6) Cl:Cl-chlorido-1κCl-tetra­hydro­furan-2κO-dichromium(II) dichloro­methane 4.5-solvate

In the mol­ecular structure of the title compound, [Cr(2)Cl(4)(C(26)H(36)N(2))(2)(C(4)H(8)O)]·4.5CH(2)Cl(2), the two Cr(II) centers are bridged by three Cl atoms, forming a dinuclear complex. Each Cr(II) center is coordinated by one chelating bis­(2,6-diisopropyl­phen­yl)ethane-1,2-diimine ligand vi...

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Detalles Bibliográficos
Autores principales: Peitz, Stephan, Peulecke, Normen, Müller, Bernd H., Spannenberg, Anke, Rosenthal, Uwe
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972152/
https://www.ncbi.nlm.nih.gov/pubmed/21578607
http://dx.doi.org/10.1107/S1600536809047266
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author Peitz, Stephan
Peulecke, Normen
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
author_facet Peitz, Stephan
Peulecke, Normen
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
author_sort Peitz, Stephan
collection PubMed
description In the mol­ecular structure of the title compound, [Cr(2)Cl(4)(C(26)H(36)N(2))(2)(C(4)H(8)O)]·4.5CH(2)Cl(2), the two Cr(II) centers are bridged by three Cl atoms, forming a dinuclear complex. Each Cr(II) center is coordinated by one chelating bis­(2,6-diisopropyl­phen­yl)ethane-1,2-diimine ligand via both N atoms. An additional chloride ion binds to one chromium center, whereas an additional tetra­hydro­furan mol­ecule coordinates to the second Cr(II) center. The coordination geometry at each Cr(II) center can be best described as distorted octa­hedral.
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spelling pubmed-29721522010-12-30 Bis[N,N′-bis­(2,6-diisopropyl­phen­yl)ethane-1,2-diimine]-1κ(2) N,N′;2κ(2) N,N′-tri-μ-trichlorido-1:2κ(6) Cl:Cl-chlorido-1κCl-tetra­hydro­furan-2κO-dichromium(II) dichloro­methane 4.5-solvate Peitz, Stephan Peulecke, Normen Müller, Bernd H. Spannenberg, Anke Rosenthal, Uwe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mol­ecular structure of the title compound, [Cr(2)Cl(4)(C(26)H(36)N(2))(2)(C(4)H(8)O)]·4.5CH(2)Cl(2), the two Cr(II) centers are bridged by three Cl atoms, forming a dinuclear complex. Each Cr(II) center is coordinated by one chelating bis­(2,6-diisopropyl­phen­yl)ethane-1,2-diimine ligand via both N atoms. An additional chloride ion binds to one chromium center, whereas an additional tetra­hydro­furan mol­ecule coordinates to the second Cr(II) center. The coordination geometry at each Cr(II) center can be best described as distorted octa­hedral. International Union of Crystallography 2009-11-14 /pmc/articles/PMC2972152/ /pubmed/21578607 http://dx.doi.org/10.1107/S1600536809047266 Text en © Peitz et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Peitz, Stephan
Peulecke, Normen
Müller, Bernd H.
Spannenberg, Anke
Rosenthal, Uwe
Bis[N,N′-bis­(2,6-diisopropyl­phen­yl)ethane-1,2-diimine]-1κ(2) N,N′;2κ(2) N,N′-tri-μ-trichlorido-1:2κ(6) Cl:Cl-chlorido-1κCl-tetra­hydro­furan-2κO-dichromium(II) dichloro­methane 4.5-solvate
title Bis[N,N′-bis­(2,6-diisopropyl­phen­yl)ethane-1,2-diimine]-1κ(2) N,N′;2κ(2) N,N′-tri-μ-trichlorido-1:2κ(6) Cl:Cl-chlorido-1κCl-tetra­hydro­furan-2κO-dichromium(II) dichloro­methane 4.5-solvate
title_full Bis[N,N′-bis­(2,6-diisopropyl­phen­yl)ethane-1,2-diimine]-1κ(2) N,N′;2κ(2) N,N′-tri-μ-trichlorido-1:2κ(6) Cl:Cl-chlorido-1κCl-tetra­hydro­furan-2κO-dichromium(II) dichloro­methane 4.5-solvate
title_fullStr Bis[N,N′-bis­(2,6-diisopropyl­phen­yl)ethane-1,2-diimine]-1κ(2) N,N′;2κ(2) N,N′-tri-μ-trichlorido-1:2κ(6) Cl:Cl-chlorido-1κCl-tetra­hydro­furan-2κO-dichromium(II) dichloro­methane 4.5-solvate
title_full_unstemmed Bis[N,N′-bis­(2,6-diisopropyl­phen­yl)ethane-1,2-diimine]-1κ(2) N,N′;2κ(2) N,N′-tri-μ-trichlorido-1:2κ(6) Cl:Cl-chlorido-1κCl-tetra­hydro­furan-2κO-dichromium(II) dichloro­methane 4.5-solvate
title_short Bis[N,N′-bis­(2,6-diisopropyl­phen­yl)ethane-1,2-diimine]-1κ(2) N,N′;2κ(2) N,N′-tri-μ-trichlorido-1:2κ(6) Cl:Cl-chlorido-1κCl-tetra­hydro­furan-2κO-dichromium(II) dichloro­methane 4.5-solvate
title_sort bis[n,n′-bis­(2,6-diisopropyl­phen­yl)ethane-1,2-diimine]-1κ(2) n,n′;2κ(2) n,n′-tri-μ-trichlorido-1:2κ(6) cl:cl-chlorido-1κcl-tetra­hydro­furan-2κo-dichromium(ii) dichloro­methane 4.5-solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972152/
https://www.ncbi.nlm.nih.gov/pubmed/21578607
http://dx.doi.org/10.1107/S1600536809047266
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AT peuleckenormen bisnnbis26diisopropylphenylethane12diimine1k2nn2k2nntrimtrichlorido12k6clclchlorido1kcltetrahydrofuran2kodichromiumiidichloromethane45solvate
AT mullerberndh bisnnbis26diisopropylphenylethane12diimine1k2nn2k2nntrimtrichlorido12k6clclchlorido1kcltetrahydrofuran2kodichromiumiidichloromethane45solvate
AT spannenberganke bisnnbis26diisopropylphenylethane12diimine1k2nn2k2nntrimtrichlorido12k6clclchlorido1kcltetrahydrofuran2kodichromiumiidichloromethane45solvate
AT rosenthaluwe bisnnbis26diisopropylphenylethane12diimine1k2nn2k2nntrimtrichlorido12k6clclchlorido1kcltetrahydrofuran2kodichromiumiidichloromethane45solvate

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