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[(Z)-O-Methyl-N-propylthiocarbamato-κS](triphenylphosphine-κP)gold(I)
In the title compound, [Au(C(5)H(10)NOS)(C(18)H(15)P)], the Au(I) atom is linearly coordinated within an S,P-donor set with distortion from an ideal linear geometry [S—Au—P = 176.71 (6)°] due to an intramolecular Au⋯O contact [2.943 (4) Å]. In the crystal structure, centrosymmetrically related mol...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972153/ https://www.ncbi.nlm.nih.gov/pubmed/21578595 http://dx.doi.org/10.1107/S1600536809046856 |
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author | Tadbuppa, Primjira P. Tiekink, Edward R. T. |
author_facet | Tadbuppa, Primjira P. Tiekink, Edward R. T. |
author_sort | Tadbuppa, Primjira P. |
collection | PubMed |
description | In the title compound, [Au(C(5)H(10)NOS)(C(18)H(15)P)], the Au(I) atom is linearly coordinated within an S,P-donor set with distortion from an ideal linear geometry [S—Au—P = 176.71 (6)°] due to an intramolecular Au⋯O contact [2.943 (4) Å]. In the crystal structure, centrosymmetrically related molecules associate via C—H⋯O interactions. |
format | Text |
id | pubmed-2972153 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29721532010-12-30 [(Z)-O-Methyl-N-propylthiocarbamato-κS](triphenylphosphine-κP)gold(I) Tadbuppa, Primjira P. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Au(C(5)H(10)NOS)(C(18)H(15)P)], the Au(I) atom is linearly coordinated within an S,P-donor set with distortion from an ideal linear geometry [S—Au—P = 176.71 (6)°] due to an intramolecular Au⋯O contact [2.943 (4) Å]. In the crystal structure, centrosymmetrically related molecules associate via C—H⋯O interactions. International Union of Crystallography 2009-11-11 /pmc/articles/PMC2972153/ /pubmed/21578595 http://dx.doi.org/10.1107/S1600536809046856 Text en © Tadbuppa and Tiekink 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Tadbuppa, Primjira P. Tiekink, Edward R. T. [(Z)-O-Methyl-N-propylthiocarbamato-κS](triphenylphosphine-κP)gold(I) |
title | [(Z)-O-Methyl-N-propylthiocarbamato-κS](triphenylphosphine-κP)gold(I) |
title_full | [(Z)-O-Methyl-N-propylthiocarbamato-κS](triphenylphosphine-κP)gold(I) |
title_fullStr | [(Z)-O-Methyl-N-propylthiocarbamato-κS](triphenylphosphine-κP)gold(I) |
title_full_unstemmed | [(Z)-O-Methyl-N-propylthiocarbamato-κS](triphenylphosphine-κP)gold(I) |
title_short | [(Z)-O-Methyl-N-propylthiocarbamato-κS](triphenylphosphine-κP)gold(I) |
title_sort | [(z)-o-methyl-n-propylthiocarbamato-κs](triphenylphosphine-κp)gold(i) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972153/ https://www.ncbi.nlm.nih.gov/pubmed/21578595 http://dx.doi.org/10.1107/S1600536809046856 |
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