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[(Z)-O-Methyl-N-propyl­thio­carbamato-κS](triphenyl­phosphine-κP)gold(I)

In the title compound, [Au(C(5)H(10)NOS)(C(18)H(15)P)], the Au(I) atom is linearly coordinated within an S,P-donor set with distortion from an ideal linear geometry [S—Au—P = 176.71 (6)°] due to an intra­molecular Au⋯O contact [2.943 (4) Å]. In the crystal structure, centrosymmetrically related mol­...

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Detalles Bibliográficos
Autores principales: Tadbuppa, Primjira P., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972153/
https://www.ncbi.nlm.nih.gov/pubmed/21578595
http://dx.doi.org/10.1107/S1600536809046856
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author Tadbuppa, Primjira P.
Tiekink, Edward R. T.
author_facet Tadbuppa, Primjira P.
Tiekink, Edward R. T.
author_sort Tadbuppa, Primjira P.
collection PubMed
description In the title compound, [Au(C(5)H(10)NOS)(C(18)H(15)P)], the Au(I) atom is linearly coordinated within an S,P-donor set with distortion from an ideal linear geometry [S—Au—P = 176.71 (6)°] due to an intra­molecular Au⋯O contact [2.943 (4) Å]. In the crystal structure, centrosymmetrically related mol­ecules associate via C—H⋯O inter­actions.
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spelling pubmed-29721532010-12-30 [(Z)-O-Methyl-N-propyl­thio­carbamato-κS](triphenyl­phosphine-κP)gold(I) Tadbuppa, Primjira P. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Au(C(5)H(10)NOS)(C(18)H(15)P)], the Au(I) atom is linearly coordinated within an S,P-donor set with distortion from an ideal linear geometry [S—Au—P = 176.71 (6)°] due to an intra­molecular Au⋯O contact [2.943 (4) Å]. In the crystal structure, centrosymmetrically related mol­ecules associate via C—H⋯O inter­actions. International Union of Crystallography 2009-11-11 /pmc/articles/PMC2972153/ /pubmed/21578595 http://dx.doi.org/10.1107/S1600536809046856 Text en © Tadbuppa and Tiekink 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tadbuppa, Primjira P.
Tiekink, Edward R. T.
[(Z)-O-Methyl-N-propyl­thio­carbamato-κS](triphenyl­phosphine-κP)gold(I)
title [(Z)-O-Methyl-N-propyl­thio­carbamato-κS](triphenyl­phosphine-κP)gold(I)
title_full [(Z)-O-Methyl-N-propyl­thio­carbamato-κS](triphenyl­phosphine-κP)gold(I)
title_fullStr [(Z)-O-Methyl-N-propyl­thio­carbamato-κS](triphenyl­phosphine-κP)gold(I)
title_full_unstemmed [(Z)-O-Methyl-N-propyl­thio­carbamato-κS](triphenyl­phosphine-κP)gold(I)
title_short [(Z)-O-Methyl-N-propyl­thio­carbamato-κS](triphenyl­phosphine-κP)gold(I)
title_sort [(z)-o-methyl-n-propyl­thio­carbamato-κs](triphenyl­phosphine-κp)gold(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972153/
https://www.ncbi.nlm.nih.gov/pubmed/21578595
http://dx.doi.org/10.1107/S1600536809046856
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