1-Methyl-4-({5-[(4-methyl­phen­yl)sulfan­yl]pent­yl}sulfan­yl)benzene

There are two independent mol­ecules in the asymmetric unit of the title compound, C(19)H(24)S(2). In both mol­ecules, the aliphatic segment of the ligand is in an all-trans conformation: the –S–(CH(2))(5)–S–bridging chain is almost planar (r.m.s. deviation for all non-H atoms = 0.0393 and 0.0796 Å...

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Autores principales: Brito, Iván, Cárdenas, Alejandro, Albanez, Joselyn, Bolte, Michael, López-Rodríguez, Matías
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972162/
https://www.ncbi.nlm.nih.gov/pubmed/21578720
http://dx.doi.org/10.1107/S1600536809044870
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author Brito, Iván
Cárdenas, Alejandro
Albanez, Joselyn
Bolte, Michael
López-Rodríguez, Matías
author_facet Brito, Iván
Cárdenas, Alejandro
Albanez, Joselyn
Bolte, Michael
López-Rodríguez, Matías
author_sort Brito, Iván
collection PubMed
description There are two independent mol­ecules in the asymmetric unit of the title compound, C(19)H(24)S(2). In both mol­ecules, the aliphatic segment of the ligand is in an all-trans conformation: the –S–(CH(2))(5)–S–bridging chain is almost planar (r.m.s. deviation for all non-H atoms = 0.0393 and 0.0796 Å in the two mol­ecules) and maximally extended. Their mean planes form dihedral angles of 4.08 (6)/20.47 (6) and 2.22 (6)/58.19 (6)° with the aromatic rings in the two mol­ecules. The crystal packing is purely governed by weak inter­molecular forces.
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spelling pubmed-29721622010-12-30 1-Methyl-4-({5-[(4-methyl­phen­yl)sulfan­yl]pent­yl}sulfan­yl)benzene Brito, Iván Cárdenas, Alejandro Albanez, Joselyn Bolte, Michael López-Rodríguez, Matías Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two independent mol­ecules in the asymmetric unit of the title compound, C(19)H(24)S(2). In both mol­ecules, the aliphatic segment of the ligand is in an all-trans conformation: the –S–(CH(2))(5)–S–bridging chain is almost planar (r.m.s. deviation for all non-H atoms = 0.0393 and 0.0796 Å in the two mol­ecules) and maximally extended. Their mean planes form dihedral angles of 4.08 (6)/20.47 (6) and 2.22 (6)/58.19 (6)° with the aromatic rings in the two mol­ecules. The crystal packing is purely governed by weak inter­molecular forces. International Union of Crystallography 2009-11-04 /pmc/articles/PMC2972162/ /pubmed/21578720 http://dx.doi.org/10.1107/S1600536809044870 Text en © Brito et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Brito, Iván
Cárdenas, Alejandro
Albanez, Joselyn
Bolte, Michael
López-Rodríguez, Matías
1-Methyl-4-({5-[(4-methyl­phen­yl)sulfan­yl]pent­yl}sulfan­yl)benzene
title 1-Methyl-4-({5-[(4-methyl­phen­yl)sulfan­yl]pent­yl}sulfan­yl)benzene
title_full 1-Methyl-4-({5-[(4-methyl­phen­yl)sulfan­yl]pent­yl}sulfan­yl)benzene
title_fullStr 1-Methyl-4-({5-[(4-methyl­phen­yl)sulfan­yl]pent­yl}sulfan­yl)benzene
title_full_unstemmed 1-Methyl-4-({5-[(4-methyl­phen­yl)sulfan­yl]pent­yl}sulfan­yl)benzene
title_short 1-Methyl-4-({5-[(4-methyl­phen­yl)sulfan­yl]pent­yl}sulfan­yl)benzene
title_sort 1-methyl-4-({5-[(4-methyl­phen­yl)sulfan­yl]pent­yl}sulfan­yl)benzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972162/
https://www.ncbi.nlm.nih.gov/pubmed/21578720
http://dx.doi.org/10.1107/S1600536809044870
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AT albanezjoselyn 1methyl454methylphenylsulfanylpentylsulfanylbenzene
AT boltemichael 1methyl454methylphenylsulfanylpentylsulfanylbenzene
AT lopezrodriguezmatias 1methyl454methylphenylsulfanylpentylsulfanylbenzene

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