N-(2,6-Dimethyl­phen­yl)-2-(2-thien­yl)acetamide

The thienyl ring in the title compound, C(14)H(15)NOS, is disordered over two diagonally opposite positions, the major component having a site-occupancy factor of 0.569 (3). The mol­ecule is highly twisted with respect to the central amide group, which is reflected in the dihedral angle formed betwe...

Descripción completa

Detalles Bibliográficos
Autores principales: Ferreira de Lima, Marcelle, de Souza, Marcus V. N., Tiekink, Edward R. T., Wardell, James L., Wardell, Solange M. S. V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972164/
https://www.ncbi.nlm.nih.gov/pubmed/21578912
http://dx.doi.org/10.1107/S1600536809049782
_version_ 1782190759858929664
author Ferreira de Lima, Marcelle
de Souza, Marcus V. N.
Tiekink, Edward R. T.
Wardell, James L.
Wardell, Solange M. S. V.
author_facet Ferreira de Lima, Marcelle
de Souza, Marcus V. N.
Tiekink, Edward R. T.
Wardell, James L.
Wardell, Solange M. S. V.
author_sort Ferreira de Lima, Marcelle
collection PubMed
description The thienyl ring in the title compound, C(14)H(15)NOS, is disordered over two diagonally opposite positions, the major component having a site-occupancy factor of 0.569 (3). The mol­ecule is highly twisted with respect to the central amide group, which is reflected in the dihedral angle formed between the thienyl and benzene rings of 77.01 (15)° [70.34 (18)° for the minor component]. In the crystal, mol­ecules self-associate into chains along [100] via N—H⋯O hydrogen bonds. The chains are reinforced by complementary C—H⋯O contacts.
format Text
id pubmed-2972164
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29721642010-12-30 N-(2,6-Dimethyl­phen­yl)-2-(2-thien­yl)acetamide Ferreira de Lima, Marcelle de Souza, Marcus V. N. Tiekink, Edward R. T. Wardell, James L. Wardell, Solange M. S. V. Acta Crystallogr Sect E Struct Rep Online Organic Papers The thienyl ring in the title compound, C(14)H(15)NOS, is disordered over two diagonally opposite positions, the major component having a site-occupancy factor of 0.569 (3). The mol­ecule is highly twisted with respect to the central amide group, which is reflected in the dihedral angle formed between the thienyl and benzene rings of 77.01 (15)° [70.34 (18)° for the minor component]. In the crystal, mol­ecules self-associate into chains along [100] via N—H⋯O hydrogen bonds. The chains are reinforced by complementary C—H⋯O contacts. International Union of Crystallography 2009-11-25 /pmc/articles/PMC2972164/ /pubmed/21578912 http://dx.doi.org/10.1107/S1600536809049782 Text en © Ferreira de Lima et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ferreira de Lima, Marcelle
de Souza, Marcus V. N.
Tiekink, Edward R. T.
Wardell, James L.
Wardell, Solange M. S. V.
N-(2,6-Dimethyl­phen­yl)-2-(2-thien­yl)acetamide
title N-(2,6-Dimethyl­phen­yl)-2-(2-thien­yl)acetamide
title_full N-(2,6-Dimethyl­phen­yl)-2-(2-thien­yl)acetamide
title_fullStr N-(2,6-Dimethyl­phen­yl)-2-(2-thien­yl)acetamide
title_full_unstemmed N-(2,6-Dimethyl­phen­yl)-2-(2-thien­yl)acetamide
title_short N-(2,6-Dimethyl­phen­yl)-2-(2-thien­yl)acetamide
title_sort n-(2,6-dimethyl­phen­yl)-2-(2-thien­yl)acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972164/
https://www.ncbi.nlm.nih.gov/pubmed/21578912
http://dx.doi.org/10.1107/S1600536809049782
work_keys_str_mv AT ferreiradelimamarcelle n26dimethylphenyl22thienylacetamide
AT desouzamarcusvn n26dimethylphenyl22thienylacetamide
AT tiekinkedwardrt n26dimethylphenyl22thienylacetamide
AT wardelljamesl n26dimethylphenyl22thienylacetamide
AT wardellsolangemsv n26dimethylphenyl22thienylacetamide

Ejemplares similares