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Carbonyl[4-(2,6-dimethylphenylamino)pent-3-en-2-onato-κ(2) N,O](triphenylphosphine-κP)rhodium(I) acetone hemisolvate
In the title compound, [Rh(C(13)H(16)NO)(C(18)H(15)P)(CO)]·0.5C(3)H(6)O, the Rh atom exhibits a square-planar coordination geometry, being coordinated by the N and O atoms of the bidentate β-diketonato ligand, a P atom from the triphenylphosphine unit and a C atom from the carbonyl group. The asymm...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972166/ https://www.ncbi.nlm.nih.gov/pubmed/21578632 http://dx.doi.org/10.1107/S160053680904817X |
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author | Venter, Gertruida J. S. Steyl, Gideon Roodt, Andreas |
author_facet | Venter, Gertruida J. S. Steyl, Gideon Roodt, Andreas |
author_sort | Venter, Gertruida J. S. |
collection | PubMed |
description | In the title compound, [Rh(C(13)H(16)NO)(C(18)H(15)P)(CO)]·0.5C(3)H(6)O, the Rh atom exhibits a square-planar coordination geometry, being coordinated by the N and O atoms of the bidentate β-diketonato ligand, a P atom from the triphenylphosphine unit and a C atom from the carbonyl group. The asymmetric unit also contains a disordered half-molecule, lying about an inversion center, of the acetone solvate. Intermolecular C—H⋯O hydrogen bonds are observed between a C—H group of the triphenylphosphine unit and a carbonyl O atom and between the methyl group of the enaminoketonato backbone and the solvent O atom. In addition, an intramolecular interaction is observed between a C—H group of the triphenylphosphine unit and the O atom of the enaminoketonato ligand. |
format | Text |
id | pubmed-2972166 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29721662010-12-30 Carbonyl[4-(2,6-dimethylphenylamino)pent-3-en-2-onato-κ(2) N,O](triphenylphosphine-κP)rhodium(I) acetone hemisolvate Venter, Gertruida J. S. Steyl, Gideon Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Rh(C(13)H(16)NO)(C(18)H(15)P)(CO)]·0.5C(3)H(6)O, the Rh atom exhibits a square-planar coordination geometry, being coordinated by the N and O atoms of the bidentate β-diketonato ligand, a P atom from the triphenylphosphine unit and a C atom from the carbonyl group. The asymmetric unit also contains a disordered half-molecule, lying about an inversion center, of the acetone solvate. Intermolecular C—H⋯O hydrogen bonds are observed between a C—H group of the triphenylphosphine unit and a carbonyl O atom and between the methyl group of the enaminoketonato backbone and the solvent O atom. In addition, an intramolecular interaction is observed between a C—H group of the triphenylphosphine unit and the O atom of the enaminoketonato ligand. International Union of Crystallography 2009-11-18 /pmc/articles/PMC2972166/ /pubmed/21578632 http://dx.doi.org/10.1107/S160053680904817X Text en © Venter et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Venter, Gertruida J. S. Steyl, Gideon Roodt, Andreas Carbonyl[4-(2,6-dimethylphenylamino)pent-3-en-2-onato-κ(2) N,O](triphenylphosphine-κP)rhodium(I) acetone hemisolvate |
title | Carbonyl[4-(2,6-dimethylphenylamino)pent-3-en-2-onato-κ(2)
N,O](triphenylphosphine-κP)rhodium(I) acetone hemisolvate |
title_full | Carbonyl[4-(2,6-dimethylphenylamino)pent-3-en-2-onato-κ(2)
N,O](triphenylphosphine-κP)rhodium(I) acetone hemisolvate |
title_fullStr | Carbonyl[4-(2,6-dimethylphenylamino)pent-3-en-2-onato-κ(2)
N,O](triphenylphosphine-κP)rhodium(I) acetone hemisolvate |
title_full_unstemmed | Carbonyl[4-(2,6-dimethylphenylamino)pent-3-en-2-onato-κ(2)
N,O](triphenylphosphine-κP)rhodium(I) acetone hemisolvate |
title_short | Carbonyl[4-(2,6-dimethylphenylamino)pent-3-en-2-onato-κ(2)
N,O](triphenylphosphine-κP)rhodium(I) acetone hemisolvate |
title_sort | carbonyl[4-(2,6-dimethylphenylamino)pent-3-en-2-onato-κ(2)
n,o](triphenylphosphine-κp)rhodium(i) acetone hemisolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972166/ https://www.ncbi.nlm.nih.gov/pubmed/21578632 http://dx.doi.org/10.1107/S160053680904817X |
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