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Carbonyl[4-(2,6-dimethyl­phenyl­amino)pent-3-en-2-onato-κ(2) N,O](triphenyl­phosphine-κP)rhodium(I) acetone hemi­solvate

In the title compound, [Rh(C(13)H(16)NO)(C(18)H(15)P)(CO)]·0.5C(3)H(6)O, the Rh atom exhibits a square-planar coordination geometry, being coordinated by the N and O atoms of the bidentate β-diketonato ligand, a P atom from the triphenyl­phosphine unit and a C atom from the carbonyl group. The asymm...

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Detalles Bibliográficos
Autores principales: Venter, Gertruida J. S., Steyl, Gideon, Roodt, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972166/
https://www.ncbi.nlm.nih.gov/pubmed/21578632
http://dx.doi.org/10.1107/S160053680904817X
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author Venter, Gertruida J. S.
Steyl, Gideon
Roodt, Andreas
author_facet Venter, Gertruida J. S.
Steyl, Gideon
Roodt, Andreas
author_sort Venter, Gertruida J. S.
collection PubMed
description In the title compound, [Rh(C(13)H(16)NO)(C(18)H(15)P)(CO)]·0.5C(3)H(6)O, the Rh atom exhibits a square-planar coordination geometry, being coordinated by the N and O atoms of the bidentate β-diketonato ligand, a P atom from the triphenyl­phosphine unit and a C atom from the carbonyl group. The asymmetric unit also contains a disordered half-mol­ecule, lying about an inversion center, of the acetone solvate. Inter­molecular C—H⋯O hydrogen bonds are observed between a C—H group of the triphenyl­phosphine unit and a carbonyl O atom and between the methyl group of the enamino­ketonato backbone and the solvent O atom. In addition, an intra­molecular inter­action is observed between a C—H group of the triphenyl­phosphine unit and the O atom of the enamino­ketonato ligand.
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spelling pubmed-29721662010-12-30 Carbonyl[4-(2,6-dimethyl­phenyl­amino)pent-3-en-2-onato-κ(2) N,O](triphenyl­phosphine-κP)rhodium(I) acetone hemi­solvate Venter, Gertruida J. S. Steyl, Gideon Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Rh(C(13)H(16)NO)(C(18)H(15)P)(CO)]·0.5C(3)H(6)O, the Rh atom exhibits a square-planar coordination geometry, being coordinated by the N and O atoms of the bidentate β-diketonato ligand, a P atom from the triphenyl­phosphine unit and a C atom from the carbonyl group. The asymmetric unit also contains a disordered half-mol­ecule, lying about an inversion center, of the acetone solvate. Inter­molecular C—H⋯O hydrogen bonds are observed between a C—H group of the triphenyl­phosphine unit and a carbonyl O atom and between the methyl group of the enamino­ketonato backbone and the solvent O atom. In addition, an intra­molecular inter­action is observed between a C—H group of the triphenyl­phosphine unit and the O atom of the enamino­ketonato ligand. International Union of Crystallography 2009-11-18 /pmc/articles/PMC2972166/ /pubmed/21578632 http://dx.doi.org/10.1107/S160053680904817X Text en © Venter et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Venter, Gertruida J. S.
Steyl, Gideon
Roodt, Andreas
Carbonyl[4-(2,6-dimethyl­phenyl­amino)pent-3-en-2-onato-κ(2) N,O](triphenyl­phosphine-κP)rhodium(I) acetone hemi­solvate
title Carbonyl[4-(2,6-dimethyl­phenyl­amino)pent-3-en-2-onato-κ(2) N,O](triphenyl­phosphine-κP)rhodium(I) acetone hemi­solvate
title_full Carbonyl[4-(2,6-dimethyl­phenyl­amino)pent-3-en-2-onato-κ(2) N,O](triphenyl­phosphine-κP)rhodium(I) acetone hemi­solvate
title_fullStr Carbonyl[4-(2,6-dimethyl­phenyl­amino)pent-3-en-2-onato-κ(2) N,O](triphenyl­phosphine-κP)rhodium(I) acetone hemi­solvate
title_full_unstemmed Carbonyl[4-(2,6-dimethyl­phenyl­amino)pent-3-en-2-onato-κ(2) N,O](triphenyl­phosphine-κP)rhodium(I) acetone hemi­solvate
title_short Carbonyl[4-(2,6-dimethyl­phenyl­amino)pent-3-en-2-onato-κ(2) N,O](triphenyl­phosphine-κP)rhodium(I) acetone hemi­solvate
title_sort carbonyl[4-(2,6-dimethyl­phenyl­amino)pent-3-en-2-onato-κ(2) n,o](triphenyl­phosphine-κp)rhodium(i) acetone hemi­solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972166/
https://www.ncbi.nlm.nih.gov/pubmed/21578632
http://dx.doi.org/10.1107/S160053680904817X
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