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Octarubidium di-μ-sulfato-κ(4) O:O′-bis[cis-dioxido-cis-disulfatotungstate(VI)]
The title compound, Rb(8)[W(2)O(4)(SO(4))(6)], was precipitated from a melt of tungsten(VI) oxide and rubidium sulfate in rubidium disulfate. The unit cell contains two discrete [{W(VI)O(2)(SO(4))(2)}(2)(μ-SO(4))(2)](8−) units connected by Rb–O coordination. The W atom is octahedrally surrounded by...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972170/ https://www.ncbi.nlm.nih.gov/pubmed/21578543 http://dx.doi.org/10.1107/S1600536809046431 |
| _version_ | 1782190761245147136 |
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| author | Ståhl, Kenny Berg, Rolf W. |
| author_facet | Ståhl, Kenny Berg, Rolf W. |
| author_sort | Ståhl, Kenny |
| collection | PubMed |
| description | The title compound, Rb(8)[W(2)O(4)(SO(4))(6)], was precipitated from a melt of tungsten(VI) oxide and rubidium sulfate in rubidium disulfate. The unit cell contains two discrete [{W(VI)O(2)(SO(4))(2)}(2)(μ-SO(4))(2)](8−) units connected by Rb–O coordination. The W atom is octahedrally surrounded by two oxide ligands, two terminal sulfate ligands and two bridging sulfate groups. One Rb atom is coordinated by eight O atoms, whereas the three other Rb atoms are coordinated by nine O atoms from sulfate and oxide groups, leading to distorted [RbO(x)] polyhedra. |
| format | Text |
| id | pubmed-2972170 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29721702010-12-30 Octarubidium di-μ-sulfato-κ(4) O:O′-bis[cis-dioxido-cis-disulfatotungstate(VI)] Ståhl, Kenny Berg, Rolf W. Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, Rb(8)[W(2)O(4)(SO(4))(6)], was precipitated from a melt of tungsten(VI) oxide and rubidium sulfate in rubidium disulfate. The unit cell contains two discrete [{W(VI)O(2)(SO(4))(2)}(2)(μ-SO(4))(2)](8−) units connected by Rb–O coordination. The W atom is octahedrally surrounded by two oxide ligands, two terminal sulfate ligands and two bridging sulfate groups. One Rb atom is coordinated by eight O atoms, whereas the three other Rb atoms are coordinated by nine O atoms from sulfate and oxide groups, leading to distorted [RbO(x)] polyhedra. International Union of Crystallography 2009-11-11 /pmc/articles/PMC2972170/ /pubmed/21578543 http://dx.doi.org/10.1107/S1600536809046431 Text en © Ståhl and Berg 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Inorganic Papers Ståhl, Kenny Berg, Rolf W. Octarubidium di-μ-sulfato-κ(4) O:O′-bis[cis-dioxido-cis-disulfatotungstate(VI)] |
| title | Octarubidium di-μ-sulfato-κ(4)
O:O′-bis[cis-dioxido-cis-disulfatotungstate(VI)] |
| title_full | Octarubidium di-μ-sulfato-κ(4)
O:O′-bis[cis-dioxido-cis-disulfatotungstate(VI)] |
| title_fullStr | Octarubidium di-μ-sulfato-κ(4)
O:O′-bis[cis-dioxido-cis-disulfatotungstate(VI)] |
| title_full_unstemmed | Octarubidium di-μ-sulfato-κ(4)
O:O′-bis[cis-dioxido-cis-disulfatotungstate(VI)] |
| title_short | Octarubidium di-μ-sulfato-κ(4)
O:O′-bis[cis-dioxido-cis-disulfatotungstate(VI)] |
| title_sort | octarubidium di-μ-sulfato-κ(4)
o:o′-bis[cis-dioxido-cis-disulfatotungstate(vi)] |
| topic | Inorganic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972170/ https://www.ncbi.nlm.nih.gov/pubmed/21578543 http://dx.doi.org/10.1107/S1600536809046431 |
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