7-Chloro-4-[(E)-(3-chloro­benzyl­idene)hydrazinyl]-1λ(4)-quinolinium 3-chloro­benzoate

The title salt, C(16)H(12)Cl(2)N(3) (+)·C(7)H(4)ClO(2) (−), features a non-planar cation, the dihedral angle between the quinolinium and benzene residues being 18.98 (10)°. The cation adopts an E conformation about the C—N bond, and the amine group is oriented towards the quinolinium residue. In the...

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Detalles Bibliográficos
Autores principales: de Souza, Marcus V. N., Howie, R. Alan, Tiekink, Edward R. T., Wardell, James L., Wardell, Solange M. S. V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972174/
https://www.ncbi.nlm.nih.gov/pubmed/21578913
http://dx.doi.org/10.1107/S1600536809049794
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author de Souza, Marcus V. N.
Howie, R. Alan
Tiekink, Edward R. T.
Wardell, James L.
Wardell, Solange M. S. V.
author_facet de Souza, Marcus V. N.
Howie, R. Alan
Tiekink, Edward R. T.
Wardell, James L.
Wardell, Solange M. S. V.
author_sort de Souza, Marcus V. N.
collection PubMed
description The title salt, C(16)H(12)Cl(2)N(3) (+)·C(7)H(4)ClO(2) (−), features a non-planar cation, the dihedral angle between the quinolinium and benzene residues being 18.98 (10)°. The cation adopts an E conformation about the C—N bond, and the amine group is oriented towards the quinolinium residue. In the crystal, N—H⋯O hydrogen bonds link two cations with two anions, forming a 20-membered {⋯OCO⋯HNC(3)NH}(2) synthon. The dimeric units are connected into a linear supra­molecular chain along [100] via π–π inter­actions [centroid–centroid distance = 3.5625 (13) Å].
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spelling pubmed-29721742010-12-30 7-Chloro-4-[(E)-(3-chloro­benzyl­idene)hydrazinyl]-1λ(4)-quinolinium 3-chloro­benzoate de Souza, Marcus V. N. Howie, R. Alan Tiekink, Edward R. T. Wardell, James L. Wardell, Solange M. S. V. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title salt, C(16)H(12)Cl(2)N(3) (+)·C(7)H(4)ClO(2) (−), features a non-planar cation, the dihedral angle between the quinolinium and benzene residues being 18.98 (10)°. The cation adopts an E conformation about the C—N bond, and the amine group is oriented towards the quinolinium residue. In the crystal, N—H⋯O hydrogen bonds link two cations with two anions, forming a 20-membered {⋯OCO⋯HNC(3)NH}(2) synthon. The dimeric units are connected into a linear supra­molecular chain along [100] via π–π inter­actions [centroid–centroid distance = 3.5625 (13) Å]. International Union of Crystallography 2009-11-25 /pmc/articles/PMC2972174/ /pubmed/21578913 http://dx.doi.org/10.1107/S1600536809049794 Text en © Souza et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
de Souza, Marcus V. N.
Howie, R. Alan
Tiekink, Edward R. T.
Wardell, James L.
Wardell, Solange M. S. V.
7-Chloro-4-[(E)-(3-chloro­benzyl­idene)hydrazinyl]-1λ(4)-quinolinium 3-chloro­benzoate
title 7-Chloro-4-[(E)-(3-chloro­benzyl­idene)hydrazinyl]-1λ(4)-quinolinium 3-chloro­benzoate
title_full 7-Chloro-4-[(E)-(3-chloro­benzyl­idene)hydrazinyl]-1λ(4)-quinolinium 3-chloro­benzoate
title_fullStr 7-Chloro-4-[(E)-(3-chloro­benzyl­idene)hydrazinyl]-1λ(4)-quinolinium 3-chloro­benzoate
title_full_unstemmed 7-Chloro-4-[(E)-(3-chloro­benzyl­idene)hydrazinyl]-1λ(4)-quinolinium 3-chloro­benzoate
title_short 7-Chloro-4-[(E)-(3-chloro­benzyl­idene)hydrazinyl]-1λ(4)-quinolinium 3-chloro­benzoate
title_sort 7-chloro-4-[(e)-(3-chloro­benzyl­idene)hydrazinyl]-1λ(4)-quinolinium 3-chloro­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972174/
https://www.ncbi.nlm.nih.gov/pubmed/21578913
http://dx.doi.org/10.1107/S1600536809049794
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