[(Z)-N-(4-Chloro­phen­yl)-O-methyl­thio­carbamato-κS](triphenyl­phosphine-κP)gold(I)

The title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], is characterized by a linear S,P-donor set with a small deviation from the ideal linearity [S—Au—P = 175.14 (5)°] due to the close approach of the O atom to the Au atom [Au⋯O = 2.882 (3) Å]. Loosely associated dimers are formed in the crystal str...

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Detalles Bibliográficos
Autores principales: Tadbuppa, Primjira P., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2972176/
https://www.ncbi.nlm.nih.gov/pubmed/21578703
http://dx.doi.org/10.1107/S1600536809050454
Descripción
Sumario:The title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], is characterized by a linear S,P-donor set with a small deviation from the ideal linearity [S—Au—P = 175.14 (5)°] due to the close approach of the O atom to the Au atom [Au⋯O = 2.882 (3) Å]. Loosely associated dimers are formed in the crystal structure through C—H⋯O inter­actions.

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