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Poly[diaqua­(μ(3)-8-oxidoquinoline-5-sulfonato-κ(4) N,O (8):O (5):O (8))nickel(II)]

In title compound, [Ni(C(9)H(5)NO(4)S)(H(2)O)(2)](n), the Ni(II) atom is coordinated by one N atom and two bridging O atoms from two 8-oxidoquinoline-5-sulfonate ligands, one sulfonate O atom from a third ligand, and two water mol­ecules in a distorted octa­hedral geometry. The two Ni(II) atoms are...

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Detalles Bibliográficos
Autores principales: Wang, Ying, Wang, Li, Xu, Jianing, Zhu, Guangshan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977084/
https://www.ncbi.nlm.nih.gov/pubmed/21583362
http://dx.doi.org/10.1107/S1600536809026105
Descripción
Sumario:In title compound, [Ni(C(9)H(5)NO(4)S)(H(2)O)(2)](n), the Ni(II) atom is coordinated by one N atom and two bridging O atoms from two 8-oxidoquinoline-5-sulfonate ligands, one sulfonate O atom from a third ligand, and two water mol­ecules in a distorted octa­hedral geometry. The two Ni(II) atoms are linked to each other through the bridging O atoms, forming a dimer. Adjacent dimers are connected through the coordination of the sulfonate O atom into a two-dimensional coordination network parallel to (010). Hydrogen bonds between the coordinated water mol­ecules and the uncoordinated O atoms of the sulfonate groups result in the construction of a three-dimensional supra­molecular structure.