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Poly[diaqua(μ(3)-8-oxidoquinoline-5-sulfonato-κ(4) N,O (8):O (5):O (8))nickel(II)]
In title compound, [Ni(C(9)H(5)NO(4)S)(H(2)O)(2)](n), the Ni(II) atom is coordinated by one N atom and two bridging O atoms from two 8-oxidoquinoline-5-sulfonate ligands, one sulfonate O atom from a third ligand, and two water molecules in a distorted octahedral geometry. The two Ni(II) atoms are...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977084/ https://www.ncbi.nlm.nih.gov/pubmed/21583362 http://dx.doi.org/10.1107/S1600536809026105 |
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author | Wang, Ying Wang, Li Xu, Jianing Zhu, Guangshan |
author_facet | Wang, Ying Wang, Li Xu, Jianing Zhu, Guangshan |
author_sort | Wang, Ying |
collection | PubMed |
description | In title compound, [Ni(C(9)H(5)NO(4)S)(H(2)O)(2)](n), the Ni(II) atom is coordinated by one N atom and two bridging O atoms from two 8-oxidoquinoline-5-sulfonate ligands, one sulfonate O atom from a third ligand, and two water molecules in a distorted octahedral geometry. The two Ni(II) atoms are linked to each other through the bridging O atoms, forming a dimer. Adjacent dimers are connected through the coordination of the sulfonate O atom into a two-dimensional coordination network parallel to (010). Hydrogen bonds between the coordinated water molecules and the uncoordinated O atoms of the sulfonate groups result in the construction of a three-dimensional supramolecular structure. |
format | Text |
id | pubmed-2977084 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29770842010-12-30 Poly[diaqua(μ(3)-8-oxidoquinoline-5-sulfonato-κ(4) N,O (8):O (5):O (8))nickel(II)] Wang, Ying Wang, Li Xu, Jianing Zhu, Guangshan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In title compound, [Ni(C(9)H(5)NO(4)S)(H(2)O)(2)](n), the Ni(II) atom is coordinated by one N atom and two bridging O atoms from two 8-oxidoquinoline-5-sulfonate ligands, one sulfonate O atom from a third ligand, and two water molecules in a distorted octahedral geometry. The two Ni(II) atoms are linked to each other through the bridging O atoms, forming a dimer. Adjacent dimers are connected through the coordination of the sulfonate O atom into a two-dimensional coordination network parallel to (010). Hydrogen bonds between the coordinated water molecules and the uncoordinated O atoms of the sulfonate groups result in the construction of a three-dimensional supramolecular structure. International Union of Crystallography 2009-07-11 /pmc/articles/PMC2977084/ /pubmed/21583362 http://dx.doi.org/10.1107/S1600536809026105 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Ying Wang, Li Xu, Jianing Zhu, Guangshan Poly[diaqua(μ(3)-8-oxidoquinoline-5-sulfonato-κ(4) N,O (8):O (5):O (8))nickel(II)] |
title | Poly[diaqua(μ(3)-8-oxidoquinoline-5-sulfonato-κ(4)
N,O
(8):O
(5):O
(8))nickel(II)] |
title_full | Poly[diaqua(μ(3)-8-oxidoquinoline-5-sulfonato-κ(4)
N,O
(8):O
(5):O
(8))nickel(II)] |
title_fullStr | Poly[diaqua(μ(3)-8-oxidoquinoline-5-sulfonato-κ(4)
N,O
(8):O
(5):O
(8))nickel(II)] |
title_full_unstemmed | Poly[diaqua(μ(3)-8-oxidoquinoline-5-sulfonato-κ(4)
N,O
(8):O
(5):O
(8))nickel(II)] |
title_short | Poly[diaqua(μ(3)-8-oxidoquinoline-5-sulfonato-κ(4)
N,O
(8):O
(5):O
(8))nickel(II)] |
title_sort | poly[diaqua(μ(3)-8-oxidoquinoline-5-sulfonato-κ(4)
n,o
(8):o
(5):o
(8))nickel(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977084/ https://www.ncbi.nlm.nih.gov/pubmed/21583362 http://dx.doi.org/10.1107/S1600536809026105 |
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