Dichlorido{2-[2-(dimethyl­ammonio)ethyl­imino­meth­yl]-6-methoxy­phenolato}zinc(II)

The structure of the title complex, [ZnCl(2)(C(12)H(18)N(2)O(2))], contains a zwitterionic Schiff base ligand. The complex adopts a distorted tetra­hedral coordination geometry around the metal centre with the Schiff base ligand coordinated in a bidentate fashion via the imine N and phenolate O atom...

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Detalles Bibliográficos
Autores principales: Datta, Amitabha, Chuang, Nien-Tsu, Huang, Jui-Hsien, Lee, Hon Man
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977086/
https://www.ncbi.nlm.nih.gov/pubmed/21583409
http://dx.doi.org/10.1107/S1600536809028220
Descripción
Sumario:The structure of the title complex, [ZnCl(2)(C(12)H(18)N(2)O(2))], contains a zwitterionic Schiff base ligand. The complex adopts a distorted tetra­hedral coordination geometry around the metal centre with the Schiff base ligand coordinated in a bidentate fashion via the imine N and phenolate O atoms. In the crystal, inter­molecular N—H⋯O and C—H⋯Cl hydrogen bonds link the mol­ecules into chains parallel to the c-glide planes.

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