Dichlorido{2-[2-(dimethyl­ammonio)ethyl­imino­meth­yl]-6-methoxy­phenolato}zinc(II)

The structure of the title complex, [ZnCl(2)(C(12)H(18)N(2)O(2))], contains a zwitterionic Schiff base ligand. The complex adopts a distorted tetra­hedral coordination geometry around the metal centre with the Schiff base ligand coordinated in a bidentate fashion via the imine N and phenolate O atom...

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Detalles Bibliográficos
Autores principales: Datta, Amitabha, Chuang, Nien-Tsu, Huang, Jui-Hsien, Lee, Hon Man
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977086/
https://www.ncbi.nlm.nih.gov/pubmed/21583409
http://dx.doi.org/10.1107/S1600536809028220
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author Datta, Amitabha
Chuang, Nien-Tsu
Huang, Jui-Hsien
Lee, Hon Man
author_facet Datta, Amitabha
Chuang, Nien-Tsu
Huang, Jui-Hsien
Lee, Hon Man
author_sort Datta, Amitabha
collection PubMed
description The structure of the title complex, [ZnCl(2)(C(12)H(18)N(2)O(2))], contains a zwitterionic Schiff base ligand. The complex adopts a distorted tetra­hedral coordination geometry around the metal centre with the Schiff base ligand coordinated in a bidentate fashion via the imine N and phenolate O atoms. In the crystal, inter­molecular N—H⋯O and C—H⋯Cl hydrogen bonds link the mol­ecules into chains parallel to the c-glide planes.
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spelling pubmed-29770862010-12-30 Dichlorido{2-[2-(dimethyl­ammonio)ethyl­imino­meth­yl]-6-methoxy­phenolato}zinc(II) Datta, Amitabha Chuang, Nien-Tsu Huang, Jui-Hsien Lee, Hon Man Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title complex, [ZnCl(2)(C(12)H(18)N(2)O(2))], contains a zwitterionic Schiff base ligand. The complex adopts a distorted tetra­hedral coordination geometry around the metal centre with the Schiff base ligand coordinated in a bidentate fashion via the imine N and phenolate O atoms. In the crystal, inter­molecular N—H⋯O and C—H⋯Cl hydrogen bonds link the mol­ecules into chains parallel to the c-glide planes. International Union of Crystallography 2009-07-22 /pmc/articles/PMC2977086/ /pubmed/21583409 http://dx.doi.org/10.1107/S1600536809028220 Text en © Datta et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Datta, Amitabha
Chuang, Nien-Tsu
Huang, Jui-Hsien
Lee, Hon Man
Dichlorido{2-[2-(dimethyl­ammonio)ethyl­imino­meth­yl]-6-methoxy­phenolato}zinc(II)
title Dichlorido{2-[2-(dimethyl­ammonio)ethyl­imino­meth­yl]-6-methoxy­phenolato}zinc(II)
title_full Dichlorido{2-[2-(dimethyl­ammonio)ethyl­imino­meth­yl]-6-methoxy­phenolato}zinc(II)
title_fullStr Dichlorido{2-[2-(dimethyl­ammonio)ethyl­imino­meth­yl]-6-methoxy­phenolato}zinc(II)
title_full_unstemmed Dichlorido{2-[2-(dimethyl­ammonio)ethyl­imino­meth­yl]-6-methoxy­phenolato}zinc(II)
title_short Dichlorido{2-[2-(dimethyl­ammonio)ethyl­imino­meth­yl]-6-methoxy­phenolato}zinc(II)
title_sort dichlorido{2-[2-(dimethyl­ammonio)ethyl­imino­meth­yl]-6-methoxy­phenolato}zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977086/
https://www.ncbi.nlm.nih.gov/pubmed/21583409
http://dx.doi.org/10.1107/S1600536809028220
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