catena-Poly[[[aqua­(1,10-phenanthro­line)zinc(II)]-μ-3,3′-(p-phenyl­ene)di­acrylato] hemihydrate]

In the title compound, {[Zn(C(12)H(8)O(4))(C(12)H(8)N(2))(H(2)O)]·0.5H(2)O}(n), each Zn(II) atom is six-coordinated by two N atoms from one 1,10-phenanthroline (phen), three carboxyl­ate O atoms from two different L ligands [H(2) L = 3,3′-(p-phenyl­ene)diacrylic acid] and one water mol­ecule in a di...

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Detalles Bibliográficos
Autores principales: Li, Ya-Ping, Sun, Da-Jun, Zang, Hu, Su, Guan-Fang, Li, Yu-Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977088/
https://www.ncbi.nlm.nih.gov/pubmed/21583394
http://dx.doi.org/10.1107/S1600536809025665
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author Li, Ya-Ping
Sun, Da-Jun
Zang, Hu
Su, Guan-Fang
Li, Yu-Lin
author_facet Li, Ya-Ping
Sun, Da-Jun
Zang, Hu
Su, Guan-Fang
Li, Yu-Lin
author_sort Li, Ya-Ping
collection PubMed
description In the title compound, {[Zn(C(12)H(8)O(4))(C(12)H(8)N(2))(H(2)O)]·0.5H(2)O}(n), each Zn(II) atom is six-coordinated by two N atoms from one 1,10-phenanthroline (phen), three carboxyl­ate O atoms from two different L ligands [H(2) L = 3,3′-(p-phenyl­ene)diacrylic acid] and one water mol­ecule in a distorted octa­hedral environment. The two L dianions are situated across inversion centres and bridge neighbouring Zn(II) centres, yielding a chain propagating parallel to [100]. O—H⋯O hydrogen bonds between the coordinated water molecule, the solvent water molecule (half-occupied) and the carboxylate O atoms further stabilize the structure.
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spelling pubmed-29770882010-12-30 catena-Poly[[[aqua­(1,10-phenanthro­line)zinc(II)]-μ-3,3′-(p-phenyl­ene)di­acrylato] hemihydrate] Li, Ya-Ping Sun, Da-Jun Zang, Hu Su, Guan-Fang Li, Yu-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Zn(C(12)H(8)O(4))(C(12)H(8)N(2))(H(2)O)]·0.5H(2)O}(n), each Zn(II) atom is six-coordinated by two N atoms from one 1,10-phenanthroline (phen), three carboxyl­ate O atoms from two different L ligands [H(2) L = 3,3′-(p-phenyl­ene)diacrylic acid] and one water mol­ecule in a distorted octa­hedral environment. The two L dianions are situated across inversion centres and bridge neighbouring Zn(II) centres, yielding a chain propagating parallel to [100]. O—H⋯O hydrogen bonds between the coordinated water molecule, the solvent water molecule (half-occupied) and the carboxylate O atoms further stabilize the structure. International Union of Crystallography 2009-07-18 /pmc/articles/PMC2977088/ /pubmed/21583394 http://dx.doi.org/10.1107/S1600536809025665 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Ya-Ping
Sun, Da-Jun
Zang, Hu
Su, Guan-Fang
Li, Yu-Lin
catena-Poly[[[aqua­(1,10-phenanthro­line)zinc(II)]-μ-3,3′-(p-phenyl­ene)di­acrylato] hemihydrate]
title catena-Poly[[[aqua­(1,10-phenanthro­line)zinc(II)]-μ-3,3′-(p-phenyl­ene)di­acrylato] hemihydrate]
title_full catena-Poly[[[aqua­(1,10-phenanthro­line)zinc(II)]-μ-3,3′-(p-phenyl­ene)di­acrylato] hemihydrate]
title_fullStr catena-Poly[[[aqua­(1,10-phenanthro­line)zinc(II)]-μ-3,3′-(p-phenyl­ene)di­acrylato] hemihydrate]
title_full_unstemmed catena-Poly[[[aqua­(1,10-phenanthro­line)zinc(II)]-μ-3,3′-(p-phenyl­ene)di­acrylato] hemihydrate]
title_short catena-Poly[[[aqua­(1,10-phenanthro­line)zinc(II)]-μ-3,3′-(p-phenyl­ene)di­acrylato] hemihydrate]
title_sort catena-poly[[[aqua­(1,10-phenanthro­line)zinc(ii)]-μ-3,3′-(p-phenyl­ene)di­acrylato] hemihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977088/
https://www.ncbi.nlm.nih.gov/pubmed/21583394
http://dx.doi.org/10.1107/S1600536809025665
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